Modulation of the photophysical properties of BODIPY dyes by substitution at their meso position.

被引：66
作者：
Banuelos, Jorge [1 ]
Arroyo-Cordoba, Ismael J. [2 ]
Valois-Escamilla, Ismael [3 ]
Alvarez-Hernandez, Alejandro [3 ]
Pena-Cabrera, Eduardo [2 ]
Hu, Rongrong [4 ]
Tang, Ben Zhong [4 ]
Esnal, Ixone [1 ]
Martinez, Virginia [1 ]
Lopez Arbeloa, Inigo [1 ]
机构：
[1] Univ Basque Country, Dept Quim Fis, EHU, E-48080 Bilbao, Spain
[2] Univ Guanajuato, Dept Quim, Guanajuato 36050, Gto, Mexico
[3] Univ Autonoma Estado Hidalgo, Ctr Invest Quim, Mineral De La Reforma 42076, Hidalgo, Mexico
[4] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China
来源：
RSC ADVANCES | 2011年 / 1卷 / 04期
关键词：
INTRAMOLECULAR CHARGE-TRANSFER; ENERGY-TRANSFER; ELECTRON-TRANSFER; BORON-DIPYRRIN; STRUCTURAL CONTROL; LASING PROPERTIES; FLUORESCENT DYES; LASER PROPERTIES; ACCEPTOR; PHOTOSTABILITY;
D O I：
10.1039/c1ra00020a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report the photophysical properties of new BODIPY derivatives monosubstituted at the central position. The presence of different functional groups induced the appearance of new photophysical processes in BODIPY dyes, such as intramolecular charge or energy transfer. These phenomena are sensitive to solvent properties (mainly the polarity) and have a potential use as fluorescent probes. Adequate modifications in their molecular structure or in the environment polarity can modulate the emission region of these fluorophores in the visible spectral region. Specifically, different processes and photophysical behaviors can be achieved depending on the excited chromophore and/or the solvent characteristics in a bichromophoric pyrene-BODIPY system.
引用
收藏
页码：677 / 684
页数：8
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