Structural study of an electroactive allyl ester thiophenoazomethine for PDMS blending

被引：0
作者：
Mulholland, Michael E. [1 ]
Filiatrault, Heather L. [1 ]
Maris, Thierry [2 ]
Skene, W. G. [1 ,3 ]
机构：
[1] Univ Montreal, Dept Chim, Lab caracterisat Photophys materiaux conjugues, 1375 ave Therese Lavoie Roux, Montreal, PQ H2V 0B3, Canada
[2] Univ Montreal, Dept Chim, Plateforme diffract rayons 10, 1375 ave Therese Lavoie Roux, Montreal, PQ H2V 0B3, Canada
[3] Univ Montreal, Inst Courtois, 1375 ave Therese Lavoie Roux, Montreal, PQ H2V 0B3, Canada
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2025年 / 1320卷
基金：
加拿大自然科学与工程研究理事会; 加拿大创新基金会;
关键词：
Conjugated azomethine; X-ray crystallography; PDMS; Blending; AZOMETHINE; POLYMERS; PALETTE; ACID;
D O I：
10.1016/j.molstruc.2024.139416
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A conjugated thiophene azomethine was prepared having pendant allyl esters. X-ray crystallography confirmed its structure and hydrogen bonding. The compound switched its absorption between 495 and 645 nm with electrochemical oxidation/neutralization and between 495 and 710 nm with chemical oxidation. The azomethine could be blended with PDMS for homogeneous elastomeric film preparation while maintaining its intrinsic color.
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页数：8
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