Pd-modified Au on Carbon as an Effective and Durable Catalyst for the Direct Oxidation of HMF to 2,5-Furandicarboxylic Acid

被引：210
|
作者：
Villa, Alberto [1 ]
Schiavoni, Marco [1 ]
Campisi, Sebastiano [1 ]
Veith, Gabriel M. [2 ]
Prati, Laura [1 ]
机构：
[1] Univ Milan, Dept Chem, I-20133 Milan, Italy
[2] Oak Ridge Natl Lab, Div Mat Sci & Technol, Oak Ridge, TN 37831 USA
来源：
CHEMSUSCHEM | 2013年 / 6卷 / 04期
关键词：
alloys; gold; hydroxymethylfurfural; oxidation; palladium; BIMETALLIC GOLD/PALLADIUM CATALYSTS; LIQUID-PHASE OXIDATION; SELECTIVE OXIDATION; AEROBIC OXIDATION; GOLD; CHEMICALS; GLYCEROL; ALCOHOL; BIOMASS;
D O I：
10.1002/cssc.201200778
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Mixed noblility: We show that the modification of a gold/carbon catalyst with platinum or palladium produces stable and recyclable catalysts for the selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA): the support and nanoparticle chemistry directly mediate the selective oxidation of terminal hydroxyl groups in bio-derived HMF. This finding is a significant advance over current conversion technology because of the technological importance of FDCA. © 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：609 / 612
页数：4
相关论文
共 50 条
  • [31] Boosting 2,5-Furandicarboxylic acid production via coating carbon over CeO2 in a Pt catalyst
    Zheng, Xiang
    Li, Chaoqun
    Mao, Haifang
    Liu, Xiaohui
    Guo, Yong
    Wang, Yanqin
    INDUSTRIAL CROPS AND PRODUCTS, 2022, 186
  • [32] Aerobic oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid in water under mild conditions
    Liu, Bing
    Ren, Yongshen
    Zhang, Zehui
    GREEN CHEMISTRY, 2015, 17 (03) : 1610 - 1617
  • [33] N-doped carbon supported Pt catalyst for base-free oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid
    Han, Xuewang
    Li, Chaoqun
    Guo, Yong
    Liu, Xiaohui
    Zhang, Yongguang
    Wang, Yanqin
    APPLIED CATALYSIS A-GENERAL, 2016, 526 : 1 - 8
  • [34] Ce-Modified MgFe-LDH Supported Au Particles: An Efficient Catalyst for Base-Free Selective Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid
    Moradi, Hanieh
    Kulinich, Sergei A.
    Wunderlich, Wilfried
    Ghiaci, Mehran
    CHEMISTRYSELECT, 2024, 9 (04):
  • [35] A novel magnetic palladium catalyst for the mild aerobic oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid in water
    Mei, Nan
    Liu, Bing
    Zheng, Judun
    Lv, Kangle
    Tang, Dingguo
    Zhang, Zehui
    CATALYSIS SCIENCE & TECHNOLOGY, 2015, 5 (06) : 3194 - 3202
  • [36] Efficient aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid on Ru/C catalysts
    Zheng, Lufan
    Zhao, Junqi
    Du, Zexue
    Zong, Baoning
    Liu, Haichao
    SCIENCE CHINA-CHEMISTRY, 2017, 60 (07) : 950 - 957
  • [37] Understanding the Role of the Acid Sites in 5-Hydroxymethylfurfural Oxidation to 2,5-Furandicarboxylic Acid Reaction over Gold Catalysts: Surface Investigation on CexZr1-xO2 Compounds
    Megias-Sayago, Cristina
    Chakarova, Kristina
    Penkova, Anna
    Lolli, Alice
    Ivanova, Svetlana
    Albonetti, Stefania
    Cavani, Fabrizio
    Antonio Odriozola, Jose
    ACS CATALYSIS, 2018, 8 (12): : 11154 - 11164
  • [38] Mechanistic Studies into the Selective Production of 2,5-furandicarboxylic Acid from 2,5-bis(hydroxymethyl)furan Using Au-Pd Bimetallic Catalyst Supported on Nitrated Carbon Material
    Liu, Yiran
    Chen, Yao
    Guan, Wen
    Cao, Yu
    Wang, Fang
    Zhang, Yunlei
    CATALYSTS, 2023, 13 (02)
  • [39] Base-free aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid in water by hydrotalcite-activated carbon composite supported gold catalyst
    Gao, Tianqi
    Gao, Tianyu
    Fang, Wenhao
    Cao, Qiue
    MOLECULAR CATALYSIS, 2017, 439 : 171 - 179
  • [40] Bimetallic Co-Mn catalyzed chemselective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid
    Zhu, Rui
    Gao, Fang
    Li, Xinglong
    MOLECULAR CATALYSIS, 2025, 580
12345