Pd-modified Au on Carbon as an Effective and Durable Catalyst for the Direct Oxidation of HMF to 2,5-Furandicarboxylic Acid

被引：210
|
作者：
Villa, Alberto [1 ]
Schiavoni, Marco [1 ]
Campisi, Sebastiano [1 ]
Veith, Gabriel M. [2 ]
Prati, Laura [1 ]
机构：
[1] Univ Milan, Dept Chem, I-20133 Milan, Italy
[2] Oak Ridge Natl Lab, Div Mat Sci & Technol, Oak Ridge, TN 37831 USA
来源：
CHEMSUSCHEM | 2013年 / 6卷 / 04期
关键词：
alloys; gold; hydroxymethylfurfural; oxidation; palladium; BIMETALLIC GOLD/PALLADIUM CATALYSTS; LIQUID-PHASE OXIDATION; SELECTIVE OXIDATION; AEROBIC OXIDATION; GOLD; CHEMICALS; GLYCEROL; ALCOHOL; BIOMASS;
D O I：
10.1002/cssc.201200778
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Mixed noblility: We show that the modification of a gold/carbon catalyst with platinum or palladium produces stable and recyclable catalysts for the selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA): the support and nanoparticle chemistry directly mediate the selective oxidation of terminal hydroxyl groups in bio-derived HMF. This finding is a significant advance over current conversion technology because of the technological importance of FDCA. © 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：609 / 612
页数：4
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