Thermo-kinetic analysis of sugarcane bagasse as a sustainable energy resource evaluation

被引:2
作者
Parmar, Pankaj [1 ]
Mukherjee, Subhrajit [1 ]
Singh, Vikas Kumar [1 ]
Meikap, B. C. [1 ,2 ]
机构
[1] Indian Inst Technol, Dept Chem Engn, Kharagpur 721302, W Bengal, India
[2] Univ Kwazulu Natal UKZN, Howard Coll Campus, Sch Chem Engn, Dept Chem Engn, ZA-4041 Durban, South Africa
关键词
Sugarcane bagasse; Pyrolysis; Thermogravimetric analysis; Activation energy; Iso-conventional methods; PYROLYSIS KINETICS; MICROCRYSTALLINE CELLULOSE; LIGNOCELLULOSIC BIOMASS; COMBUSTION; PARAMETERS; FUEL; STRAW; CRYSTALLINITY; DECOMPOSITION; SIMULATION;
D O I
10.1016/j.tsep.2024.102836
中图分类号
O414.1 [热力学];
学科分类号
摘要
Sugarcane bagasse was used as energy resources. Thermogravimetric analysis was performed at varying heating rates of 10, 20, 30, and 40 degrees C/min, within the temperature range of 25 to 900 degrees C. Using the iso-conversional models like Flynn-Wall-Ozawa (FWO), Friedman, Kissinger-Akahira-Sunose (KAS), and Starink, kinetics and thermodynamics were examined, and the Coats-Redfern (CR) model-fitting technique was used to identify the reaction mechanism. The pre-exponential factors were ascertained by applying the Coats-Refern method. According to KAS, FOW, Starink, and Friedman techniques, the average activation energy (Ea) values were found to be 323.46, 168.89, 162.52, and 174.70 kJ/mol, respectively. Thermodynamic characteristics indicate, sugarcane bagasse is a potential feedstock. The pyrolysis reaction was spontaneous, generating sufficient quantity of energy. This research can offer a theoretical foundation for thermochemical conversion of sugarcane bagasse and applications.
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页数:13
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