Gasification of the Char Residues with High Ash Content by Carbon Dioxide

被引:4
作者
Xue, Junjie [1 ]
Dong, Zhen [1 ]
Chen, Hao [1 ,2 ]
Zhang, Mengyuan [1 ]
Zhao, Yufeng [1 ]
Chen, Yanpeng [1 ]
Chen, Shanshan [1 ]
机构
[1] PetroChina, Res Inst Petr Explorat & Dev, Beijing 100083, Peoples R China
[2] China Univ Min & Technol, Key Lab CBM Resource & Reservoir Format Proc, Xuzhou 221008, Peoples R China
关键词
gasification; char; modelling; high ash content; RANDOM PORE MODEL; FLUID-SOLID REACTIONS; CO2; GASIFICATION; COAL CHAR; STEAM GASIFICATION; STRUCTURAL MODEL; MOVING BOUNDARY; BIOMASS; TEMPERATURE; KINETICS;
D O I
10.3390/en17174432
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
To increase the carbon conversion of char in gasification, this paper aimed to reveal the gasification behaviours of char residues. Char residues with different ash contents in this work were prepared from Shenmu char and Tejing char. Those char residues were gasified by different CO2 gas mixtures at different temperatures. The gasification process of char residue was different from the end stage of the gasification process of the corresponding raw char: the gasification rate of the char residue increased at first and then decreased, whereas the gasification rate of the corresponding raw char kept decreasing during the end stage of gasification. The highest gasification rate was achieved at a lower conversion in the gasification of char residue than in the gasification of the corresponding raw char. Catalytic minerals, high temperature, and high CO2 partial pressure benefited the gasification of gasified char residues. The char residues that contained more catalytic minerals were more reactive in gasification and were less sensitive to changes in temperature and CO2 partial pressure. The Modified Random Pore Model (MRPM) and Random Pore Model (RPM) were used to predict the gasification kinetics of the chars, and the MRPM describes the gasification processes of gasified char residues well.
引用
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页数:35
相关论文
共 52 条
[1]   Gasification of coal char in H2O/CO2 atmospheres: Evolution of surface morphology and pore structure [J].
Bai, Yonghui ;
Lv, Peng ;
Yang, Xuhao ;
Gao, Meiqi ;
Zhu, Shenghua ;
Yan, Lunjing ;
Li, Fan .
FUEL, 2018, 218 :236-246
[2]   Kinetics of rice husk char gasification [J].
Bhat, A ;
Bheemarasetti, JVR ;
Rao, TR .
ENERGY CONVERSION AND MANAGEMENT, 2001, 42 (18) :2061-2069
[3]  
BHATIA SK, 1980, AICHE J, V26, P379, DOI 10.1002/aic.690260308
[4]   POPULATION BALANCE APPROACH TO THE MODELING OF SOLID-PHASE REACTIONS [J].
BHATIA, SK ;
PERLMUTTER, DD .
AICHE JOURNAL, 1979, 25 (02) :298-306
[5]   A RANDOM PORE MODEL FOR FLUID-SOLID REACTIONS .2. DIFFUSION AND TRANSPORT EFFECTS [J].
BHATIA, SK ;
PERLMUTTER, DD .
AICHE JOURNAL, 1981, 27 (02) :247-254
[6]  
BP, 2023, STAT REV WORLD EN
[7]   A power generation system with integrated supercritical water gasification of coal and CO2 capture [J].
Chen, Zhewen ;
Zhang, Xiaosong ;
Han, Wei ;
Gao, Lin ;
Li, Sheng .
ENERGY, 2018, 142 :723-730
[8]  
Crelling J., 2008, Applied Coal Petrology: The Role of Petrology in Coal Utilization
[9]   Characteristics of high temperature C-CO2 gasification reactivity of Victorian brown coal char and its blends with high ash fusion temperature bituminous coal [J].
Dai, Baiqian ;
Hoadley, Andrew ;
Zhang, Lian .
FUEL, 2017, 202 :352-365
[10]   Characterisation of the morphological changes and interactions in char, slag and ash during CO2 gasification of rice straw and lignite [J].
Ding, Lu ;
Gong, Yan ;
Wang, Yifei ;
Wang, Fuchen ;
Yu, Guangsuo .
APPLIED ENERGY, 2017, 195 :713-724