Simple Solution Plasma Synthesis of Ni@NiO as High-Performance Anode Material for Lithium-Ion Batteries Application

Pursuing of straightforward and cost-effective methods for synthesizing high-performance anode materials for lithium-ion batteries is a topic of significant interest. This study elucidates a one-step synthesis approach for a conversion composite using glow discharge in a nickel formate solution, yielding a composite precursor comprising metallic nickel, nickel hydroxide, and basic nickel salts. Subsequent annealing of the precursor facilitated the formation of the Ni@NiO composite, exhibiting exceptional electrochemical properties as anode material in Li-ion batteries: a capacity of approximately 1000 mAh g-1, cyclic stability exceeding 100 cycles, and favorable rate performance (200 mAh g-1 at 10 A g<M-.1). Comparative analysis across various methods for synthesizing NiO-based materials underscored the superiority of the Ni@NiO composite. Furthermore, an assessment of resource costs demonstrated the cost-effectiveness and scalability of the approach in terms of resource consumption per Ah. Lastly, the integration of a Ni@NiO anode with an NMC532 cathode in a full battery highlights Ni@NiO's potential for conversion anodes, achieving a practical gravimetric energy density of 92 Wh kg-1. This study presents a novel one-step synthesis of Ni@NiO composite, showcasing outstanding electrochemical performance (1000 mAh g-1 at 0.05 A g-1 and 200 Ah g-1 at 10 A g-1), cost-effectiveness, and scalability. It performs well in full battery systems with NMC 532 cathode (92 Wh kg-1), making it a promising candidate for advanced lithium-ion battery energy storage solutions. image