Towards highly dense electrolytes at lower sintering temperature (∼1200 ° C): Optimization strategies for BaCe0.7Zr0.1CuxY0.2-xO3-δ in SOFCs

High-conducting and long-term stable proton-conducting electrolytes are of utmost importance. This study investigates the synthesis and characterization of BaCe0.7Zr0.1CuxY0.2-xO3-delta (BCZCu(x)Y; x = 0, 0.005, 0.01, 0.02, 0.05, and 0.1) electrolytes tailored for proton-conducting solid oxide fuel cells (SOFCs). Through Cu2+ doping at the B-site of BaCe0.7Zr0.1Y0.2O3-delta (BCZY), a successful reduction of the sintering temperature to 1200 degrees C was achieved. BCZCu(0.02)Y exhibited a high relative density of approx. 98.1% at this temperature, but beyond 2 mol% Cu doping, the appearance of a BaCuO2 secondary phase adversely impacted conductivity. The electronic properties of BCZY and BCZCuxY are elucidated via partial density of states (PDOS) analysis, revealing optimized crystal structures and band gap reductions (from approx. 1.9 eV-1.1 eV) upon Cu doping. Notably, BCZCu(0.02)Y demonstrated a commendable conductivity, with values of 3.5 x 10(-2) S. cm(-1) in air and 4.8 x 10(-2) S. cm(-1) in a moist atmosphere at 750 degrees C. Remarkably, excellent electrochemical stability was observed in a moist hydrogen atmosphere for up to 450 h at 600 degrees C. Single cells incorporating BCZCu(0.02)Y electrolytes exhibited peak power densities of 380 mW/cm(2) at 750 degrees C. The incorporation of 2 mol% Cu2+ in the BCZY lattice holds promise for achieving low-temperature sintering and high-performance proton-conducting SOFCs.