Pickering Emulsions in Catalytic Processes

被引:7
作者
Guzman, Eduardo [1 ,2 ]
机构
[1] Univ Complutense Madrid, Fac Ciencias Quim, Dept Quim Fis, Plaza Ciencias 2,Ciudad Univ, Madrid 28040, Spain
[2] Univ Complutense Madrid, Inst Pluridisciplinar, Paseo Juan XXIII 1,Ciudad Univ, Madrid 28040, Spain
关键词
Biphasic systems; Catalytic process; Chemical reactions; Efficiency; Pickering emulsions; HYDROPHOBIZED IN-SITU; SILICA NANOPARTICLES; PHOTOCATALYTIC DEGRADATION; INTERFACIAL BIOCATALYSIS; SELECTIVE HYDROGENATION; COLLOIDAL PARTICLES; SOLID NANOPARTICLES; BIPHASIC REACTIONS; ENZYME; HYDRODEOXYGENATION;
D O I
10.1002/cctc.202400856
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Pickering emulsions, which are emulsions stabilized by solid particles adsorbed at the interface between two immiscible liquids, provide a highly versatile platform for catalytic processes and offer distinct advantages over conventional systems. These emulsions combine the benefits of traditional biphasic catalysis with enhanced contact between reactive species due to their large interfacial area, which contribute to their high catalytic efficiency. Furthermore, Pickering emulsions offer significant advantages in catalytic processes, including improved extraction efficiency, a wider range of operational variables, the possibility of continuous operation, and the ease of recovery of the emulsifier and/or catalyst. Moreover, through strategic selection and design of solid particles, researchers can tailor interfacial properties to optimize catalytic performance, selectivity and stability. This comprehensive review discusses recent breakthroughs in Pickering emulsion research and their applications in catalysis, examining how Pickering emulsions have transformed catalytic methodologies. By discussing the latest developments, this review demonstrates the potential of Pickering emulsions as a catalyst platform and highlights their role in advancing sustainable and efficient catalytic processes. The utilization of Pickering emulsions in catalytic processes offers significant advantages for enhancing conversion, selectivity, and yield in chemical reactions. Yet, unlocking their full potential hinges on the development of innovative techniques for precise interfacial manipulation, which has become a crucial aspect in maximizing the effectiveness of this approach in various industrial applications. image
引用
收藏
页数:34
相关论文
共 140 条
[1]   Impact of Pickering Emulsions Composition on Lipase Catalyzed Peroxyacetic Acid Synthesis [J].
Adomi, Lemuel ;
Drews, Anja .
CHEMIE INGENIEUR TECHNIK, 2024, 96 (04) :535-544
[2]   Pickering emulsions: Preparation processes, key parameters governing their properties and potential for pharmaceutical applications [J].
Albert, Claire ;
Beladjine, Mohamed ;
Tsapis, Nicolas ;
Fattal, Elias ;
Agnely, Florence ;
Huang, Nicolas .
JOURNAL OF CONTROLLED RELEASE, 2019, 309 :302-332
[3]   TEMPO-Grafted Polystyrene/Polymethacrylate Organosiloxane Janus Nanohybrids as Efficient Pickering Interfacial Catalyst for Selective Aerobic Oxidation of Cinnamyl Alcohol [J].
Ali, Badusha Mohamad ;
Yu, Ziqi ;
Tao, Zhengyuan ;
Zhang, Tangxin ;
Wang, Lei ;
He, Chenbing ;
Zhang, Hao ;
Wang, Jianli .
ACS APPLIED MATERIALS & INTERFACES, 2024, 16 (16) :20409-20418
[4]  
Ansorge-Schumacher M. B., 2022, FRONT CATAL, V2
[5]   Floating Photocatalysts for Effluent Refinement Based on Stable Pickering Cellulose Foams and Graphitic Carbon Nitride (g-C3N4) [J].
Anusuyadevi, Prasaanth Ravi ;
Riazanova, Anastasia, V ;
Hedenqvist, Mikael S. ;
Svagan, Anna J. .
ACS OMEGA, 2020, 5 (35) :22411-22419
[6]   Effect of Particle Wettability and Particle Concentration on the Enzymatic Dehydration of n-Octanaloxime in Pickering Emulsions [J].
Bago Rodriguez, Ana Maria ;
Schober, Lukas ;
Hinzmann, Alessa ;
Groger, Harald ;
Binks, Bernard P. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (03) :1450-1457
[7]   Colloidal Particles at a Range of Fluid-Fluid Interfaces [J].
Binks, Bernard P. .
LANGMUIR, 2017, 33 (28) :6947-6963
[8]   Direct Measurement of Contact Angles of Silica Particles in Relation to Double Inversion of Pickering Emulsions [J].
Binks, Bernard Paul ;
Isa, Lucio ;
Tyowua, Andrew Terhemen .
LANGMUIR, 2013, 29 (16) :4923-4927
[9]   Particles as surfactants - similarities and differences [J].
Binks, BP .
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2002, 7 (1-2) :21-41
[10]   Two-Way Photoswitching Using One Type of Near-Infrared Light, Upconverting Nanoparticles, and Changing Only the Light Intensity [J].
Boyer, John-Christopher ;
Carling, Carl-Johan ;
Gates, Byron D. ;
Branda, Neil R. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (44) :15766-15772