Surface modification of nanofiltration membrane using 2D-black mica@graphene oxide nanocomposite with improved performance in water treatment

被引:1
作者
Irani-nezhad, Mahsa Haddad [1 ,2 ]
Khataee, Alireza [1 ,3 ,4 ]
Vatanpour, Vahid [5 ,6 ,7 ]
Arefi-Oskoui, Samira [1 ]
Orooji, Yasin [8 ]
机构
[1] Univ Tabriz, Fac Chem, Res Lab Adv Water & Wastewater Treatment Proc, Dept Appl Chem, Tabriz 5166616471, Iran
[2] Tabriz Univ Med Sci, Food & Drug Adm, Tabriz 5165994611, Iran
[3] Istanbul Tech Univ, Dept Chem Engn, TR-34469 Istanbul, Turkiye
[4] Istanbul Tech Univ, ITU Synthet Fuels & Chem Technol Ctr ITU SENTEK, TR-34469 Istanbul, Turkiye
[5] Kharazmi Univ, Fac Chem, Dept Appl Chem, Tehran 1571914911, Iran
[6] Istanbul Tech Univ, Environm Engn Dept, TR-34469 Istanbul, Turkiye
[7] Istanbul Tech Univ, Natl Res Ctr Membrane Technol MEM TEK, TR-34469 Istanbul, Turkiye
[8] Zhejiang Normal Univ, Coll Geog & Environm Sci, Jinhua 321004, Peoples R China
关键词
2D-black mica; Graphene oxide; Liquid phase exfoliation; Surface modification membrane; Nanofiltration; INTERFACIAL POLYMERIZATION; FRAMEWORK MEMBRANES; THIN-FILM; REMOVAL; NANOPARTICLES; STABILITY; DYES; FABRICATION; COMPOSITES; SEPARATION;
D O I
10.1016/j.seppur.2024.129133
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
It is still a challenge to attain robust stable graphene oxide (GO) based filtration membranes for maintaining freshwater resources, which have an efficacious capacity to salts, drugs, and dyes separation from water. Here, an easy and efficient method has been reported for this challenge via GO and exfoliated black mica (EB) nanosheet intercalation. The structural and morphological characteristics of the prepared EB@GO and membranes were investigated by various characterization analyses. Mica's influence on the performance of the membrane was improved by decreasing its thickness after the exfoliation process. In comparison with the nascent GO membrane, the EB:GO (B:G) membrane demonstrated both improved water flux (from 22.1 L/m(2)h to 58.2 L/m(2)h) and boosted salts removal capacity (i.e., MgCl2 (from 70.30 % to 87.34 %)). Also, this membrane can still reject dyes and drugs at high percentages (>90 %). Meanwhile, due to the B:G membrane's outstanding long-time performance, antibacterial effects against both gram-positive and gram-negative bacteria, and the ubiquitous van der Waals forces between two-dimensional materials, it can be developed to manufacture stable and highly efficient filtration membranes.
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页数:11
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