2D Covalent Organic Framework Covalently Anchored with Carbon Nanotube as High-Performance Cathodes for Lithium and Sodium-Ion Batteries

被引:4
作者
Biswas, Sandip [1 ]
Pramanik, Atin [2 ]
Dey, Anupam [1 ]
Chattopadhyay, Shreyasi [2 ]
Pieshkov, Tymofii S. [2 ,3 ]
Bhattacharyya, Sohini [2 ]
Ajayan, Pulickel M. [2 ]
Maji, Tapas Kumar [1 ]
机构
[1] Jawaharlal Nehru Ctr Adv Sci Res, Int Ctr Mat Sci, Sch Adv Mat SAMat, Chem & Phys Mat Unit,Mol Mat Lab, Bangalore 560064, India
[2] Rice Univ, Dept Mat Sci & NanoEngn, Houston, TX 77005 USA
[3] Rice Univ, Smalley Curl Inst, Appl Phys Grad Program, Houston, TX 77005 USA
关键词
carbon nanotube; covalent-organic frameworks; heterostructure; Li-ion battery; Na-ion battery; ELECTRODE MATERIALS; CHALLENGES; STORAGE; SYSTEM;
D O I
10.1002/smll.202406173
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Covalent organic frameworks (COFs), featuring structural diversity, permanent porosity, and functional versatility, have emerged as promising electrode materials for rechargeable batteries. To date, amorphous polymer, COF, or their composites are mostly explored in lithium-ion batteries (LIBs), while their research in other alkali metal ion batteries is still in infancy. This can be due to the challenges that arise from large volume changes, slow diffusion kinetics, and inefficient active site utilization by the large Na+ or K+ ion. Herein, microwave-assisted imide-based 2D COF, TAPB-NDA covalently connected with amine-functionalized carbon nanotubes (TAPB-NDA@CNT) targeting the application in both Li-/Na-ion batteries, is synthesized. As-synthesized, TAPB-NDA@CNT50 displays the good performance as LIB cathode with a specific capacity of approximate to 138 mAh g-1 at 25 mA g-1, long cycling stability (81.2% retention after 2000 cycles at 300 mA g-1), with excellent reversible capacity retention of approximate to 79.6%. Similarly, TAPB-NDA@CNT50, when employed in sodium-ion battery (SIB), exhibited 136.7 mAh g-1 specific capacity at 25 mA g-1, retained approximate to 80% of the reversible capacity after 1000 cycles at 300 mA g-1 and showing excellent rate performance. The structural advantage of TAPB-NDA@CNT will encourage researchers to design COF-based cathodes for the alkali ion batteries. 2D imide COF (TAPB-NDA)-based composites by covalently linking with amine functionalized carbon nanotube are synthesized via microwave assisted route and characterized. These composites are explored as electrode material for lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs). The electrode material shows outstanding electrochemical performances with high specific capacities, long cycling stability, and excellent rate capabilities, making it a promising cathode material for LIBs and SIBs. image
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页数:12
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