Deciphering electrochemical methanol production

被引：0

作者：

Ringe, Stefan ^{[1
]}

机构：

[1] Korea Univ, Dept Chem, Seoul, South Korea

来源：

NATURE CATALYSIS | 2024年 / 7卷 / 09期

关键词：

CO2;

D O I：

10.1038/s41929-024-01224-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Methanol selectivity is uncommon among CO2 reduction electrocatalysts. A notable exception is the cobalt phthalocyanine catalyst supported on carbon nanotubes, yet the mechanism is still poorly understood. Now, two studies use a variety of analytical approaches to investigate the mechanism of the process including the role of alkali cations.

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收藏

页码：955 / 956

页数：2

相关论文

共 14 条

[1] Aqueous Electrochemical Reduction of Carbon Dioxide and Carbon Monoxide into Methanol with Cobalt Phthalocyanine [J].

Boutin, Etienne ;

Wang, Min ;

Lin, John C. ;

Mesnage, Matthieu ;

Mendoza, Daniela ;

Lassalle-Kaiser, Benedikt ;

Hahn, Christopher ;

Jaramillo, Thomas F. ;

Robert, Marc .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (45) :16172-16176

[2] Heterogeneous molecular catalysts for electrocatalytic CO2 reduction [J].

Corbin, Nathan ;

Zeng, Joy ;

Williams, Kindle ;

Manthiram, Karthish .

NANO RESEARCH, 2019, 12 (09) :2093-2125

[3] High-Performance Electrochemical CO2 Reduction Cells Based on Non-noble Metal Catalysts [J].

Lu, Xu ;

Wu, Yueshen ;

Yuan, Xiaolei ;

Huang, Ling ;

Wu, Zishan ;

Xuan, Jin ;

Wang, Yifei ;

Wang, Hailiang .

ACS ENERGY LETTERS, 2018, 3 (10) :2527-2532

[4] Cation effects on electrocatalytic reduction processes at the example of the hydrogen evolution reaction [J].

Ringe, Stefan .

CURRENT OPINION IN ELECTROCHEMISTRY, 2023, 39

[5] Approaching in-depth mechanistic understanding of electrochemical hydrogen conversion from computational simulations [J].

Ringe, Stefan .

CHEM CATALYSIS, 2021, 1 (06) :1160-1162

[6] Double layer charging driven carbon dioxide adsorption limits the rate of electrochemical carbon dioxide reduction on Gold [J].

Ringe, Stefan ;

Morales-Guio, Carlos G. ;

Chen, Leanne D. ;

Fields, Meredith ;

Jaramillo, Thomas F. ;

Hahn, Christopher ;

Chan, Karen .

NATURE COMMUNICATIONS, 2020, 11 (01)

[7] Understanding cation effects in electrochemical CO2 reduction [J].

Ringe, Stefan ;

Clark, Ezra L. ;

Resasco, Joaquin ;

Walton, Amber ;

Seger, Brian ;

Bell, Alexis T. ;

Chan, Karen .

ENERGY & ENVIRONMENTAL SCIENCE, 2019, 12 (10) :3001-3014

[8] Strain enhances the activity of molecular electrocatalysts via carbon nanotube supports [J].

Su, Jianjun ;

Musgrave, Charles B. ;

Song, Yun ;

Huang, Libei ;

Liu, Yong ;

Li, Geng ;

Xin, Yinger ;

Xiong, Pei ;

Li, Molly Meng-Jung ;

Wu, Haoran ;

Zhu, Minghui ;

Chen, Hao Ming ;

Zhang, Jianyu ;

Shen, Hanchen ;

Tang, Ben Zhong ;

Robert, Marc ;

Goddard, William A., III ;

Ye, Ruquan .

NATURE CATALYSIS, 2023, 6 (09) :818-828

[9] Three-Dimensional Graphene-Supported Cobalt Phthalocyanine as Advanced Electrocatalysts for Oxygen Reduction Reaction [J].

Sun, Chongyun ;

Li, Zhongfang ;

Zhong, Xizhan ;

Wang, Suwen ;

Yin, Xiaoyan ;

Wang, Likai .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2018, 165 (02) :F24-F31

[10] Molecularly Dispersed Cobalt Phthalocyanine Mediates Selective and Durable CO2 Reduction in a Membrane Flow Cell [J].

Wu, Xuefeng ;

Sun, Ji Wei ;

Liu, Peng Fei ;

Zhao, Jia Yue ;

Liu, Yuanwei ;

Guo, Lisheng ;

Dai, Sheng ;

Yang, Hua Gui ;

Zhao, Huijun .

ADVANCED FUNCTIONAL MATERIALS, 2022, 32 (11)