Unveiling the aggregation-induced chromic emission of triazine anchored BODIPYs

被引:0
作者
Satardekar, Pranay [1 ]
Chaudhari, Vaishali [2 ]
Siddiqui, Zahir Ali [1 ,3 ]
Lambud, Sushil [1 ]
Sekar, Nagaiyan [3 ]
Bhosale, Rajesh [4 ]
More, Sandeep [1 ]
机构
[1] Inst Chem Technol, Dept Fibres & Text Proc Technol, Mumbai 400019, Maharashtra, India
[2] Indrashil Univ, Sch Sci, Dept Chem, Mehsana 382470, Gujarat, India
[3] Inst Chem Technol, Dept Special Chem Technol, Mumbai 400019, Maharashtra, India
[4] Ganpat Univ, Ctr Adv Res Studies, Mehsana 384012, Gujarat, India
关键词
DENSITY-FUNCTIONAL THERMOCHEMISTRY; INTRAMOLECULAR CHARGE-TRANSFER; FLUORESCENCE; DYES; RED; DERIVATIVES; SUBSTITUENTS; CHEMISTRY; BEHAVIOR; PROBES;
D O I
10.1039/d4nj03757j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
BODIPY derivatives based on 2,4,6-trichloro-1,3,5-triazine have been successfully synthesized and characterized. These molecular systems demonstrate restricted intramolecular rotation (RIR) and J-aggregation, leading to aggregation-induced chromic emission (AICE), with notable green-red fluorescence color switching. Additionally, these derivatives exhibit distinctive self-assembly behaviour and solid-state emission properties. These findings showcase their potential for diverse applications across multiple fields. Triazine-based BODIPY dyes exhibiting restricted intramolecular rotation and J-aggregation, leading to aggregation-induced chromic emission (AICE) with green-to-red emission color switching and self-assembly behaviour in the aggregated state.
引用
收藏
页码:17215 / 17225
页数:11
相关论文
共 75 条
  • [31] Computational chemistry, systems biology and toxicology. Harnessing the chemistry of life: revolutionizing toxicology. A commentary
    Kimber, Ian
    Humphris, Colin
    Westmoreland, Carl
    Alepee, Nathalie
    Dal Negro, Gianni
    Manou, Irene
    [J]. JOURNAL OF APPLIED TOXICOLOGY, 2011, 31 (03) : 206 - 209
  • [32] Koopmans T., 1934, Physica, V1, P104, DOI [10.1016/S0031-8914(34)90011-2, DOI 10.1016/S0031-8914(34)90011-2]
  • [33] SELF-CONSISTENT MOLECULAR-ORBITAL METHODS .20. BASIS SET FOR CORRELATED WAVE-FUNCTIONS
    KRISHNAN, R
    BINKLEY, JS
    SEEGER, R
    POPLE, JA
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1980, 72 (01) : 650 - 654
  • [34] Emission behavior of perimidine attached BODIPY and its response to acid/base
    Li, Xiaochuan
    Sun, SaiSai
    Kim, Ick Jin
    Son, Young-A
    [J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2017, 654 (01) : 131 - 138
  • [35] Ligands T. P., 2009, HELV CHIM ACTA, V92, P2414, DOI [10.1002/hlca.200900189, DOI 10.1002/HLCA.200900189]
  • [36] Bodipy dyes bearing oligo(ethylene glycol) groups on the meso-phenyl ring: tuneable solid-state photoluminescence and highly efficient OLEDs
    Liu, Cui-Lian
    Chen, Yong
    Shelar, Deepak P.
    Li, Cong
    Cheng, Gang
    Fu, Wen-Fu
    [J]. JOURNAL OF MATERIALS CHEMISTRY C, 2014, 2 (28) : 5471 - 5478
  • [37] Recent Progress of BODIPY Dyes With Aggregation-Induced Emission
    Liu, Zhipeng
    Jiang, Zhiyong
    Yan, Ming
    Wang, Xiaoqing
    [J]. FRONTIERS IN CHEMISTRY, 2019, 7
  • [38] Aggregation induced emission enhancement and chromism properties of a vinyl bridged naphthalene diimide dimer
    Long, Haijun
    Guo, De
    Wang, Liyuan
    Liu, Zitong
    Li, Shayu
    Liang, Xianfeng
    Chen, Yanlin
    Yang, Zhiwei
    Li, Jing
    Dong, Lichun
    Tan, Luxi
    [J]. DYES AND PIGMENTS, 2022, 203
  • [39] Structural modification strategies for the rational design of red/NIR region BODIPYs
    Lu, Hua
    Mack, John
    Yang, Yongchao
    Shen, Zhen
    [J]. CHEMICAL SOCIETY REVIEWS, 2014, 43 (13) : 4778 - 4823
  • [40] Aggregation-induced emission of 1-methyl-1,2,3,4,5-pentaphenylsilole
    Luo, JD
    Xie, ZL
    Lam, JWY
    Cheng, L
    Chen, HY
    Qiu, CF
    Kwok, HS
    Zhan, XW
    Liu, YQ
    Zhu, DB
    Tang, BZ
    [J]. CHEMICAL COMMUNICATIONS, 2001, (18) : 1740 - 1741