Unveiling the aggregation-induced chromic emission of triazine anchored BODIPYs

被引:0
作者
Satardekar, Pranay [1 ]
Chaudhari, Vaishali [2 ]
Siddiqui, Zahir Ali [1 ,3 ]
Lambud, Sushil [1 ]
Sekar, Nagaiyan [3 ]
Bhosale, Rajesh [4 ]
More, Sandeep [1 ]
机构
[1] Inst Chem Technol, Dept Fibres & Text Proc Technol, Mumbai 400019, Maharashtra, India
[2] Indrashil Univ, Sch Sci, Dept Chem, Mehsana 382470, Gujarat, India
[3] Inst Chem Technol, Dept Special Chem Technol, Mumbai 400019, Maharashtra, India
[4] Ganpat Univ, Ctr Adv Res Studies, Mehsana 384012, Gujarat, India
关键词
DENSITY-FUNCTIONAL THERMOCHEMISTRY; INTRAMOLECULAR CHARGE-TRANSFER; FLUORESCENCE; DYES; RED; DERIVATIVES; SUBSTITUENTS; CHEMISTRY; BEHAVIOR; PROBES;
D O I
10.1039/d4nj03757j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
BODIPY derivatives based on 2,4,6-trichloro-1,3,5-triazine have been successfully synthesized and characterized. These molecular systems demonstrate restricted intramolecular rotation (RIR) and J-aggregation, leading to aggregation-induced chromic emission (AICE), with notable green-red fluorescence color switching. Additionally, these derivatives exhibit distinctive self-assembly behaviour and solid-state emission properties. These findings showcase their potential for diverse applications across multiple fields. Triazine-based BODIPY dyes exhibiting restricted intramolecular rotation and J-aggregation, leading to aggregation-induced chromic emission (AICE) with green-to-red emission color switching and self-assembly behaviour in the aggregated state.
引用
收藏
页码:17215 / 17225
页数:11
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