Green and Kubo forge the arrow of time

被引:0
作者
Baroni, Stefano [1 ,2 ]
机构
[1] SISSA Scuola Int Super Studi Avanzati, I-34136 Trieste, Italy
[2] CNR Ist Officina Mat, SISSA Unit, I-34136 Trieste, Italy
关键词
Transport theory; diffusion; irreversibility; IRREVERSIBLE-PROCESSES; INVARIANCE;
D O I
10.1080/00268976.2024.2388300
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Transport theory describes the response of a macroscopic current to a thermodynamic force, thus producing entropy and apparently violating time-reversal symmetry. In this note I report a pedagogical derivation of the Green-Kubo formula for transport coefficients, based on elementary equilibrium statistical mechanics and static response theory, that highlights the intrinsically dynamical nature of this formula and showcases the relation between the apparent breach of time-reversal symmetry and the non-commutativity of the low-frequency / low-wavevector limits of the conserved-density susceptibilities, from which the formula can be established. [GRAPHICS] .
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页数:8
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