5-Methoxymethyl furfural production by acid heterogeneous catalytic etherification of 5-hydroxymethyl furfural

被引：3

作者：

Diaz-Maizkurrena, P. ^{[1
]}

Requies, J. M. ^{[1
]}

Iriondo, A. ^{[1
]}

Arias, P. L. ^{[1
]}

Mariscal, R. ^{[2
]}

机构：

[1] Sch Engn UPV EHU, Plaza Ingeniero Torres Quevedo 1, Bilbao 48013, Spain

[2] Inst Catalysis & Petrochemistry ICP CSIC, Grp Sustainable Energy & Chem EQS, C Marie Curie 2,Campus Cantoblanco, Madrid 28049, Spain

来源：

CATALYSIS TODAY | 2024年 / 426卷

关键词：

HMF; MMF; Zeolites; Non-noble metals; Br & oslash; nsted acid sites; Lewis acid sites; PYRIDINE ADSORPTION; FAST PYROLYSIS; ZEOLITES; CONVERSION; BIOMASS; EXCHANGE; NH3-TPD; CD3CN; SITES; PROBE;

D O I：

10.1016/j.cattod.2023.114374

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The use of non-edible raw materials from agriculture as a form of biomass to obtain carbon-based compounds is the most viable solution to replace fossil resources. Within this, 5-hydroxymethyl furfural (HMF) is a platform monomer from which other high value-added monomers are obtained, such as 2,5-furandicarboxylic acid (FDCA), a compound that can be obtained from 5-methoxymethyl furfural (MMF), and which can be used as a fuel, fuel additive or polymer precursor. Several catalysts (mostly zeolites) have been tested to produce MMF. Specifically, with a ZSM-5 zeolite a yield towards this compound of 97 % has been achieved, carrying out the reaction in a batch reactor for 5 h. Through the characterization of the catalysts, a strong correlation has been observed between the acidity of these catalysts and their effectiveness in the reaction of HMF through MMF.

引用

页数：11

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