Synthesis of Nonclassical Heteroaryl C-Glycosides via Decarboxylative C-H Glycosylation

被引：2
作者：
Zhang, Cuimei [1 ]
He, Dongqin [2 ]
Ma, Zhaohui [3 ]
Wang, Mi [1 ]
Zhu, Yafei [1 ]
Liu, Yan [2 ]
Chen, Jian [1 ]
Guo, Li [1 ]
Lv, Guanghui [1 ,3 ]
Wu, Yong [1 ]
机构：
[1] Sichuan Univ, West China Sch Pharm, Key Lab Drug Targeting & Drug Delivery Syst, Educ Minist,Dept Med Chem, Chengdu 610041, Sichuan, Peoples R China
[2] Hubei Univ Med, Taihe Hosp, Hubei Prov Clin Res Ctr Umbil Cord Blood Hematopoi, Dept Pediat, Shiyan 442000, Hubei, Peoples R China
[3] Hubei Univ Med, Taihe Hosp, Hubei Prov Clin Res Ctr Umbil Cord Blood Hematopoi, Dept Pharm, Shiyan 442000, Hubei, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 89卷 / 14期
关键词：
PROTEIN GLYCOSYLATION; NUCLEOSIDES; ANALOGS; MILD;
D O I：
10.1021/acs.joc.4c00868
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A photoredox-promoted decarboxylative C-H glycosylation for the synthesis of nonclassical heteroaryl C-glycosides is reported. This methodology is characterized by an exceedingly simple reaction system, high diastereoselectivity, and good functional group tolerance. Moreover, the operational procedure is simple, and the gram-scale reaction highlights the practical applicability of this protocol.
引用
收藏
页码：10112 / 10126
页数：15
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