Study on Fe-doped BiOBr with enhanced visible photocatalytic activity for the degradation of levofloxacin

被引:2
|
作者
Liu, Lu [1 ]
Wang, Kun [1 ]
Zhang, Jingwen [1 ]
Li, Yinghua [1 ]
Li, Yuxin [1 ]
Yang, Ning [1 ]
Guo, Xin [1 ]
机构
[1] Northeastern Univ, Sch Resources & Civil Engn, Shenyang, Peoples R China
关键词
BiOBr; Fe-ions doping; Photocatalysis; Semiconductors; Optical materials and properties; QUANTUM DOTS;
D O I
10.1016/j.matlet.2024.137122
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this study, Fe-doped BiOBr photocatalysts were prepared by hydrothermal method. Due to the unique flowerlike structure of the composite materials, when the Fe-ions doping amount was 3 mol%, the degradation rate of levofloxacin was 85.06 % within 30 min. After 5 cycles, the degradation rate of Fe-BiOBr could still reach 83.46 %, it exhibited good photocatalytic activity. In addition, the possible degradation products and pathways were predicted by LC-MS, and toxicity analysis of intermediates was carried out. In addition, the free radical capture experiments and electron paramagnetic resonance (EPR) revealed that h+, center dot OH and center dot O-2 were the main reactive species, which in turn suggested the possible photocatalytic mechanism for the Fe-doped BiOBr system.
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页数:5
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