NPh3-Mediated WO3-Photocatalyzed Semiheterogeneous Hydroxylation of Aryl and Alkyl Boronic Acids

被引：20

作者：

Huang, Xiao-Jun ^{[1
]}

Ji, Hong-Tao ^{[1
]}

Li, Xiao ^{[1
]}

Luo, Qing-Xia ^{[1
]}

Li, Ting ^{[1
]}

Ou, Li-Juan ^{[2
]}

He, Wei-Min ^{[1
]}

机构：

[1] Univ South China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China

[2] Hunan Inst Technol, Sch Mat Sci & Engn, Hengyang 421002, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 89卷 / 15期

关键词：

CATALYZED HYDROXYLATION; OXIDATION; PHOTOCATALYSIS; METAL;

D O I：

10.1021/acs.joc.4c00885

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

With an inexpensive and commercially available WO3 semiconductor as the heterogeneous photocatalyst, a catalytic amount of NPh3 as the single-electron donor, and ambient air as the single-electron acceptor and oxygen source, the semiheterogeneous photocatalytic hydroxylation of alkyl and aryl boronic acids was developed. A broad range of hydroxylated compounds can be obtained in excellent yields.

引用

页码：10654 / 10659

页数：6

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