Effect of Extrusion Process on Microstructure, Corrosion Properties, and Mechanical Properties of Micro-Alloyed Mg-Zn-Ca-Zr Alloy

被引:0
作者
Yu, Zemin [1 ]
Hu, Wenxin [1 ]
Chen, Zhiqiang [1 ]
Shi, Lei [1 ]
Yang, Lei [2 ,3 ]
Jin, Jianfeng [2 ,3 ]
Zhang, Erlin [2 ,3 ]
机构
[1] Baotou Res Inst Rare Earths, State Key Lab Baiyunobo Rare Earth Resource Res &, Baotou 014030, Peoples R China
[2] Northeastern Univ, Sch Mat Sci & Engn, Key Lab Anisotropy & Texture Mat, Minist Educ China, Shenyang 110819, Peoples R China
[3] Northeastern Univ, Res Ctr Met Wires, Shenyang 110819, Peoples R China
关键词
Mg-Zn-Ca-Zr alloy; extrusion; Zr-rich phase; corrosion properties; mechanical properties; MAGNESIUM ALLOYS; PURE MAGNESIUM; BEHAVIOR; RESISTANCE; SUSCEPTIBILITY; DEGRADATION;
D O I
10.3390/ma17174263
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effect of the extrusion process on the microstructure, corrosion, and mechanical properties of Mg-Zn-Ca-Zr alloy has been investigated. Zn and Ca were both in a solid solution and only the Zr-rich phase was observed in the homogenized and extruded alloys. The Zr-rich phase was obviously refined after extrusion. The corrosion rate of the homogenized alloy decreased by about 25% after extrusion. This is because the refined Zr-rich phase was easier to cover with the deposited corrosion products, which reduced the cathodic reaction activity of the Zr-rich phase. The corrosion rate is similar for the alloys extruded at 320 degrees C and 350 degrees C since the size and distribution of the Zr-rich phase were not different in the two conditions. The alloy extruded at 320 degrees C has a smaller grain size and better comprehensive mechanical properties.
引用
收藏
页数:14
相关论文
共 63 条
[1]   Corrosion behavior of Mg-Zn-Zr-RE alloys under physiological environment - Impact on mechanical integrity and biocompatibility [J].
AbdelGawad, Marwa ;
Usman, Chaudhry A. ;
Shunmugasamy, Vasanth C. ;
Karaman, Ibrahim ;
Mansoor, Bilal .
JOURNAL OF MAGNESIUM AND ALLOYS, 2022, 10 (06) :1542-1572
[2]   Corrosion behaviour of AZ31 magnesium alloy with different grain sizes in simulated biological fluids [J].
Alvarez-Lopez, M. ;
Dolores Pereda, Maria ;
del Valle, J. A. ;
Fernandez-Lorenzo, M. ;
Garcia-Alonso, M. C. ;
Ruano, O. A. ;
Escudero, M. L. .
ACTA BIOMATERIALIA, 2010, 6 (05) :1763-1771
[3]   Improved corrosion resistance of Mg-8Sn-1Zn-1Al alloy subjected to low-temperature indirect extrusion [J].
Baek, Soo-Min ;
Kang, Jeong Su ;
Kim, Jong Chan ;
Kim, Beomcheol ;
Park, Sung Soo ;
Shin, Hyung-Joon .
CORROSION SCIENCE, 2018, 141 :203-210
[4]   Microstructure and bio-corrosion behavior of Mg-Zn and Mg-Zn-Ca alloys for biomedical applications [J].
Bakhsheshi-Rad, H. R. ;
Hamzah, E. ;
Fereidouni-Lotfabadi, A. ;
Daroonparvar, M. ;
Yajid, M. A. M. ;
Mezbahul-Islam, M. ;
Kasiri-Asgarani, M. ;
Medraj, M. .
MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION, 2014, 65 (12) :1178-1187
[5]   Microstructure and mechanical and corrosion properties of hot-extruded Mg-Zn-Ca-(Mn) biodegradable alloys [J].
Bazhenov, V. E. ;
Li, A., V ;
Komissarov, A. A. ;
Koltygin, A., V ;
Tavolzhanskii, S. A. ;
Bautin, V. A. ;
Voropaeva, O. O. ;
Mukhametshina, A. M. ;
Tokar, A. A. .
JOURNAL OF MAGNESIUM AND ALLOYS, 2021, 9 (04) :1428-1442
[6]   The relation between microstructure and corrosion behavior of Mg-Y-RE-Zr alloys [J].
Ben-Hamu, G. ;
Eliezer, D. ;
Shin, K. S. ;
Cohen, S. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2007, 431 (1-2) :269-276
[7]   The relation between microstructure and corrosion behavior of AZ80 Mg alloy following different extrusion temperatures [J].
Ben-Haroush, M. ;
Ben-Hamu, G. ;
Eliezer, D. ;
Wagner, L. .
CORROSION SCIENCE, 2008, 50 (06) :1766-1778
[8]   Grain character influences on corrosion of ECAPed pure magnesium [J].
Birbilis, N. ;
Ralston, K. D. ;
Virtanen, S. ;
Fraser, H. L. ;
Davies, C. H. J. .
CORROSION ENGINEERING SCIENCE AND TECHNOLOGY, 2010, 45 (03) :224-230
[9]   Corrosion behaviour in salt spray and in 3.5% NaCl solution saturated with Mg(OH)2 of as-cast and solution heat-treated binary Mg-X alloys: X = Mn, Sn, Ca, Zn, Al, Zr, Si, Sr [J].
Cao, Fuyong ;
Shi, Zhiming ;
Song, Guang-Ling ;
Liu, Ming ;
Atrens, Andrej .
CORROSION SCIENCE, 2013, 76 :60-97
[10]  
Cao P., 2003, P LIGHT MET TECHN C