Mild construction of N-fused polycyclic compounds via Rh(III)/EosinY co-catalyze C-H activation

被引：5

作者：

Wu, Zhouping ^{[1
,2
]}

Lv, Guanghui ^{[3
]}

Lin, Zheng ^{[1
,2
]}

Tang, Jiangyan ^{[1
,2
]}

Chen, Jian ^{[1
,2
]}

Liu, Jianghong ^{[1
,2
]}

Hai, Li ^{[1
,2
]}

Wu, Yong ^{[1
,2
]}

机构：

[1] Sichuan Univ, West China Sch Pharm, Sichuan Engn Lab Plant Sourced Drug, Key Lab Drug Targeting & Drug Delivery Syst,Educ M, Chengdu 610041, Peoples R China

[2] Sichuan Univ, Sichuan Res Ctr Drug Precis Ind Technol, West China Sch Pharm, Chengdu 610041, Peoples R China

[3] Hubei Univ Med, Taihe Hosp, Dept Pharm, 32 South Renmin Rd, Shiyan 442000, Peoples R China

来源：

GREEN SYNTHESIS AND CATALYSIS | 2024年 / 5卷 / 02期

关键词：

N -fused polycyclic compounds; C -H activation; Rh(III) catalyst and photocatalyst; Iodonium ylides; Energy transfer process; PHOTOREDOX CATALYSIS; IODONIUM YLIDES; RHODIUM; FUNCTIONALIZATION; CARBENES; INDOLES;

D O I：

10.1016/j.gresc.2022.11.002

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The construction of N-fused polycyclic compounds at room temperature via the combination of transition-metal catalyst and photocatalyst has been reported. This novel work has successfully realized LED irradiated C-H activation of iodonium ylides. The strategy shows wide substrate scope and ideal functional group tolerance. Our work would be useful for the construction of various heterocyclic compounds.

引用

页码：108 / 111

页数：4

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