Preparation of copper and phosphorus co-doped three-dimensional layered hexagonal cobalt nanodisks for monitoring nitrobenzene in environmental pollutants

被引:7
作者
Chang, Mengrou [1 ]
Hao, Lin [2 ]
Hu, Mingjie [1 ]
Wang, Huan [1 ]
Zhang, Yufan [1 ]
机构
[1] Hebei Univ, Coll Chem & Mat Sci, Coll Life Sci, Key Lab Analyt Sci & Technol Hebei Prov,Key Lab Me, Baoding 071002, Peoples R China
[2] Hebei Agr Univ, Coll Sci, Baoding 071001, Peoples R China
关键词
Transition metal phosphides; Heteroatom doping; Three-dimensional cobalt nanodisks; Electrochemical sensor; Nitrobenzene; INTERCALATED ANIONS; GOLD NANOPARTICLES; FACILE SYNTHESIS; EVOLUTION; COMPOSITE; EFFICIENT; ELECTRODE; EXCHANGE;
D O I
10.1016/j.jallcom.2024.176541
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study, copper and phosphorus co-doped three-dimensional layered hexagonal cobalt nanodiscs were synthesized using a rapid and simple method and were applied for the detection of nitrobenzene, an environmental pollutant. The incorporation of phosphorus into the nanodiscs created catalytic sites, while the addition of copper increased the density of active sites and facilitated rapid charge transfer. Co-doping phosphorus and copper allowed the CuCo NDs/P composite material to exhibit excellent catalytic activity towards nitrobenzene. Experimental results demonstrated that CuCo NDs/P had a lower detection limit and a broader linear range. Additionally, the sensor was tested on natural water samples to evaluate its practical feasibility, indicating significant potential for further development.
引用
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页数:8
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