Metal-free radical selenothiocyanation of terminal and internal alkynes

被引：1

作者：

Chen, Jiabin ^{[1
]}

Bai, Xiaoyan ^{[1
]}

Jiang, Haobo ^{[1
]}

Zhao, Cong ^{[1
]}

Li, Ya ^{[1
]}

Chu, Mingming ^{[2
]}

Li, Yiming ^{[2
]}

Zhang, Min ^{[3
]}

Chen, Lu ^{[1
]}

机构：

[1] Wuyi Univ, Sch Environm & Chem Engn, Jiangmen Key Lab Synthet Chem & Cleaner Prod, Jiangmen 529020, Peoples R China

[2] Jiaxing Univ, Coll Biol Chem Sci & Engn, Jiaxing 314001, Peoples R China

[3] South China Univ Technol, Sch Chem & Chem Engn, Key Lab Funct Mol Engn Guangdong Prov, Wushan Rd 381, Guangzhou 510641, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 74期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1039/d4cc03391d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report herein a synthetic strategy for the generation of direct selenothiocyanation from both terminal and internal alkynes via a radical process. Alkynes derived from bioactive molecules, such as l(-)-borneol and l-menthol, are suitable for selenothiocyanation reaction. This method features metal-free conditions and readily available reagents. A method for inducing direct selenothiocyanation from both terminal and internal alkynes through a radical process is proposed under metal-free conditions.

引用

页码：10196 / 10199

页数：4