Maximizing the electrochemical efficiency of Ce doped SnFe2O4 through hydrothermal route for supercapacitor applications

被引:47
作者
Ashan, Muhammad [1 ]
Alyousef, Haifa A. [2 ]
Alrowaily, Albandari W. [2 ]
Alotaibi, B. M. [2 ]
Al-Harbi, Nuha [3 ]
Somaily, H. H. [4 ]
Aslam, Muhammad [5 ,6 ]
Ahmad, Khursheed [7 ]
Aman, Salma [8 ]
机构
[1] Govt Grad Coll, Dept Chem, Taunsa Sharif 32100, Pakistan
[2] Princess Nourah Bint Abdulrahman Univ, Coll Sci, Dept Phys, POB 84428, Riyadh 11671, Saudi Arabia
[3] Umm Al Qura Univ, Fac Appl Sci, Dept Phys, Mecca, Saudi Arabia
[4] King Khalid Univ, Fac Sci, Dept Phys, POB 9004, Abha, Saudi Arabia
[5] Ural Fed Univ, Inst Phys & Technol, Mira Str19, Ekaterinburg 620002, Russia
[6] Gomal Univ, GCBB, Dera Ismail Khan 29050, Pakistan
[7] Yeungnam Univ, Sch Mat Sci & Engn, Gyongsan 38541, South Korea
[8] Bahauddin Zakariya Univ, Inst Phys, Multan, Pakistan
关键词
Stannous ferrite (SnFe2O4); Ce doped tin ferrite (Ce-SnFe2O4); Doping; Hydrothermal method; Supercapacitors; REDUCED GRAPHENE OXIDE; ELECTRODE MATERIAL; PERFORMANCE; FERRITE; MN; NANOPARTICLES; NANOSHEETS; CO;
D O I
10.1016/j.electacta.2024.144840
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Improving the ion/charge transport kinetics, chemical activity of surfaces and reduction of ion-diffusion pathways in metallic oxides with nanoscale structures is an important challenge in the field of supercapacitor development. Materials with outstanding characteristics have been achieved by a metal-doping method that enhances electrical conductivity. Herein, cerium-doped stannous ferrite (Ce-SnFe2O4) was developed by an easy and simple hydrothermal method. Different physical and electrochemical analysis methods were utilized to examine the manufactured electrode samples. The material showed a maximum specific capacitance (C-s) of 1216 F g(-1) and specific capacity (Q(s)) of 645 C g(-1) at 1 A g(-1), along with outstanding cyclic durability across 5000 cycles. The specific energy (S-E) was also assessed to be 47.7 Wh Kg(-1) and the specific power (S-P) was 265 W kg(-1) at 1 A g(-1). Moreover, synthesized doped material demonstrates the lower value of impedance (R-ct = 0.11 Omega). Hence, the incorporation of cerium resulted in an improvement in the material's dampness which let the electrolyte penetrate the material more effectively. Additionally, the electrolyte came into complete contact with the active site, which resulted in a rise in the efficiency of the interface transmission. Based on these findings, the Cedoped SnFe2O4 material has the potential to be utilized in future supercapacitor applications.
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页数:12
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