Hydrochemical and Formation Mechanism Studies of Groundwater in Quaternary Aquifer in a Northern Plain of China: An Example of Beijing Plain

Beijing Plain is a very active part of Beijing city regarding the socio-economic and human activities of the region. Over the past four decades, Beijing's economic development and the continuous drought for nearly 10 years in the 2000s have negatively impacted the groundwater quantity and quality. Therefore, it is necessary to investigate the present situation of groundwater chemistry in this region to develop a comprehensive database and orientation for future research on groundwater quality evaluation. Mathematical statistics, Piper's trilinear diagram, Gibbs plots, the ion ratio method and PHREEQC software 3.7.3 were used to analyze the groundwater hydrogeochemical characteristics and formation mechanisms of the quaternary aquifers of the Beijing Plain area. Hydrogeochemical results indicated that the groundwater is slightly alkaline, with pH values ranging from 6.76 to 8.65 and an average value of 7.92. The order of major cations in groundwater was Ca2+ > Na+ > Mg2+ > K+ with average values of 66.54 mg/L, 50.58 mg/L, 23.78 mg/L, and 1.81 mg/L, respectively, while the order of major anions was HCO3- > SO42- > Cl- with average values of 284.89 mg/L, 52.1 mg/L and 35.5 mg/L, respectively. The groundwater chemical types are Mg-Ca-Cl-HCO3, Na-Ca-HCO3, Mg-Ca-HCO3 and Mg-Na-HCO3. Research on the main influencing factors and PHREEQC hydrogeochemical inverse simulations results along the four pathways selected confirmed that rock weathering with sulfate, silicate and carbonate rock mineral dissolution and Na+, Mg2+ and Ca2+ ion reaction exchange influenced groundwater hydrogeochemical characteristics of the quaternary aquifers of the Beijing Plain area. Understanding the formation mechanisms of hydrogeochemistry in quaternary plains provides guidance for future studies and, through suggestions and case studies, facilitates decision-making by policy-makers on the sustainable management of groundwater resources.