The thermodynamic behavior of binary systems isoamyl acetate and alcohol through experimental measurements and modeling

The thermodynamic and transport properties are experimentally determined for three binary liquid mixtures consisting of isoamyl acetate and different alcohols at ambient pressure and in temperature range. From measured density, viscosity and refractive index are calculated excess molar volume, viscosity and refractive index deviations. Isentropic compressibility and excess molar Gibbs free energies of viscous flow are determined combining density with speed of sound and viscosity data. All mentioned derived properties are used to analyze the changes taking place in investigated binary systems causing deviations from the ideal mixture. Additionally, partial molar volumes and excess partial molar volumes, as well as thermal expansion coefficient, were calculated. The results are discussed in terms of chemical structure of used compounds and the influence of the alcohol present in the mixture on the mixture behavior. The study showed that higher influence has branching of the alcohol molecule and position of the -OH group rather than the length of the primary alcohol chain. Beside the experimental part, the modeling of the excess molar volume and viscosity was also performed, and the percentage deviations are used as the indicator of model performance in terms of model approach, predictive or correlative, and number of model parameters, one to three parameters optimized.