The effect of rare earth catalysts for the conversion of sucrose to lactic acid

被引:1
作者
Song, Yuanbo [1 ]
Jin, Mengyu [1 ]
Chen, Wenbo [1 ]
Zhang, Yalei [1 ,2 ,3 ,4 ]
Shen, Zheng [1 ,2 ,3 ,4 ]
机构
[1] Tongji Univ, Inst New Rural Dev, Sch Elect & Informat Engn, Shanghai 201804, Peoples R China
[2] Tongji Univ, Coll Environm Sci & Engn, State Key Lab Pollut Control & Resources Reuse, Shanghai 200092, Peoples R China
[3] Minist Agr & Rural Affairs, Key Lab Rural Toilet & Sewage Treatment Technol, Shanghai 201804, Peoples R China
[4] Shanghai Inst Pollut Control & Ecol Secur, Shanghai 200092, Peoples R China
基金
中国国家自然科学基金;
关键词
Lactic acid; Sucrose; Y/Yb-Beta; Lewis acid; Reaction pathways; BETA ZEOLITE CATALYST; SN-BETA; BIOMASS; ENERGY; SUGARS; BASE;
D O I
10.1007/s13399-024-06036-9
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Utilizing sucrose, a readily accessible disaccharide, to produce the versatile platform chemical lactic acid offers advantages over monosaccharides. This study introduced a novel catalyst comprising Beta zeolites modified with the rare earth elements Yttrium (Y) and Ytterbium (Yb). Under optimal hydrothermal conditions (210 degrees C, 4 h), the 1 mmol/g Y/Yb Beta catalyst achieves yields of up to 45.2% and 47.1% for the conversion of sucrose to lactic acid. The yield of 5-hydroxymethylfurfural (HMF) is approximately 10%. Py-IR analysis confirmed that compared to Beta, the 1 mmol/g Y/Yb Beta catalyst has more Lewis acid sites, which promote lactate production and inhibit the production of HMF byproducts. This work speculated possible reaction pathways based on experimental results and acid characterization.
引用
收藏
页码:13797 / 13805
页数:9
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