Syntheses, structures, and characterization of two new Zn(<sc>ii</sc>)/Cd(<sc>ii</sc>) complexes with phenanthroline derivative

被引：0
|
作者：
Song, Yuzhu [1 ,2 ]
Li, Wei [2 ]
Jin, Ruiwen [2 ]
Feng, Jingdong [1 ,2 ]
机构：
[1] Jilin Normal Univ, Minist Educ, Key Lab Preparat & Applicat Environm Friendly Mat, Changchun 130103, Peoples R China
[2] Jilin Normal Univ, Dept Chem, Siping 136000, Peoples R China
来源：
MAIN GROUP METAL CHEMISTRY | 2024年 / 47卷 / 01期
关键词：
Zn(ii) complex; Cd(ii) complex; phenanthroline derivative; Hirshfeld surface analysis; CRYSTAL-STRUCTURE; COORDINATION; FLUORESCENCE; CLUSTERS;
D O I：
10.1515/mgmc-2024-0009
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Under hydrothermal conditions, two novel Zn(ii)/Cd(ii) complexes [Cd-2(L)(4)(Cl)(2)]<middle dot>(SO4) (1) and {[Zn-2(L)(2)(Sip)(OH)]<middle dot>H2O} n (2) (L = 2-(2,6-dichlorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline, NaH(2)Sip = 5-sulfoisophthalic acid monosodium salt) were successfully synthesized and characterized by elemental analysis, single-crystal X-ray diffraction, and Hirshfeld surface analysis. The study reveals that complex 1 is constructed from the binuclear [Cd2L4Cl2] unit, and the [Cd2L4Cl2] units are linked via C-H & ctdot;pi and C-Cl & ctdot;pi interactions into 2D supramolecular layers. These 2D layers are further connected to generate 3D structures by N-H & ctdot;O and N-H & ctdot;S hydrogen bonds. Complex 2 exhibits a 1D double-chain structure consisting of a binuclear [Zn2L2(OH)] unit, which is further connected by pi-pi interaction to shape a 2D supramolecular structure.
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页数：8
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