Syntheses, structures, and characterization of two new Zn(<sc>ii</sc>)/Cd(<sc>ii</sc>) complexes with phenanthroline derivative

被引：0
|
作者：
Song, Yuzhu [1 ,2 ]
Li, Wei [2 ]
Jin, Ruiwen [2 ]
Feng, Jingdong [1 ,2 ]
机构：
[1] Jilin Normal Univ, Minist Educ, Key Lab Preparat & Applicat Environm Friendly Mat, Changchun 130103, Peoples R China
[2] Jilin Normal Univ, Dept Chem, Siping 136000, Peoples R China
来源：
MAIN GROUP METAL CHEMISTRY | 2024年 / 47卷 / 01期
关键词：
Zn(ii) complex; Cd(ii) complex; phenanthroline derivative; Hirshfeld surface analysis; CRYSTAL-STRUCTURE; COORDINATION; FLUORESCENCE; CLUSTERS;
D O I：
10.1515/mgmc-2024-0009
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Under hydrothermal conditions, two novel Zn(ii)/Cd(ii) complexes [Cd-2(L)(4)(Cl)(2)]<middle dot>(SO4) (1) and {[Zn-2(L)(2)(Sip)(OH)]<middle dot>H2O} n (2) (L = 2-(2,6-dichlorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline, NaH(2)Sip = 5-sulfoisophthalic acid monosodium salt) were successfully synthesized and characterized by elemental analysis, single-crystal X-ray diffraction, and Hirshfeld surface analysis. The study reveals that complex 1 is constructed from the binuclear [Cd2L4Cl2] unit, and the [Cd2L4Cl2] units are linked via C-H & ctdot;pi and C-Cl & ctdot;pi interactions into 2D supramolecular layers. These 2D layers are further connected to generate 3D structures by N-H & ctdot;O and N-H & ctdot;S hydrogen bonds. Complex 2 exhibits a 1D double-chain structure consisting of a binuclear [Zn2L2(OH)] unit, which is further connected by pi-pi interaction to shape a 2D supramolecular structure.
引用
收藏
页数：8
相关论文
共 50 条
  • [1] Development of a novel Cd(<sc>ii</sc>) metal complex for solvent-sensitive detection of Zn(<sc>ii</sc>) and Mg(<sc>ii</sc>) with the formation of Cd(<sc>ii</sc>)-Zn(<sc>ii</sc>)/Cd(<sc>ii</sc>)-Mg(<sc>ii</sc>) complexes and their application in effective Schottky devices
    Sathapat, Dibyendu
    Das, Mainak
    Das, Manik
    Das, Uttam Kumar
    Bag, Arijit
    Laha, Soumik
    Ray, Partha Pratim
    Samanta, Bidhan Chandra
    Maity, Tithi
    NEW JOURNAL OF CHEMISTRY, 2024, 48 (04) : 1837 - 1849
  • [2] Syntheses, crystal structures, and characterizations of two new Zn(<sc>ii</sc>)/Ni(<sc>ii</sc>) coordination polymers constructed by N-donor ligands and sulfate-bridge
    Wang, Huilin
    Li, Sai
    Zhang, Hua
    Su, Beihao
    Wang, Xiuyan
    MAIN GROUP METAL CHEMISTRY, 2025, 48 (01)
  • [3] Isonicotinate-Zn(<sc>ii</sc>)/Cd(<sc>ii</sc>) bridged dicobaloximes: synthesis, characterization and electrocatalytic proton reduction studies
    Yadav, Jitendra Kumar
    Mishra, Anjali
    Mishra, Gaurav Kumar
    Pal, Sarvesh Kumar
    Narvekar, Kedar Umakant
    Rahaman, Ahibur
    Singh, Nanhai
    Lama, Prem
    Kumar, Kamlesh
    NEW JOURNAL OF CHEMISTRY, 2023, 47 (44) : 20583 - 20593
  • [4] Recovery of Co(<sc>ii</sc>), Ni(<sc>ii</sc>) and Zn(<sc>ii</sc>) using magnetic nanoparticles (MNPs) at circumneutral pH
    O'Neill, Katie E. B.
    Biswakarma, Jagannath
    Crane, Rich
    Byrne, James M.
    ENVIRONMENTAL SCIENCE-NANO, 2025, 12 (04) : 2371 - 2382
  • [5] Complexation of drug amifampridine with Cu(<sc>ii</sc>), Zn(<sc>ii</sc>) and Cd(<sc>ii</sc>) ions, and its dimerization with the magic of Mn(<sc>ii</sc>) salts. Potential anti-COVID-19 and anticancer activities
    Hajibabaei, Farshid
    Movafagh, Samaneh Sanei
    Salehzadeh, Sadegh
    Gable, Robert William
    DALTON TRANSACTIONS, 2024, 53 (03) : 1066 - 1086
  • [6] Aspergillus fumigatus ZrfC Zn(<sc>ii</sc>) transporter scavengers zincophore-bound Zn(<sc>ii</sc>)
    Garstka, Kinga
    Potoczniak, Gabriela
    Kozlowski, Henryk
    Rowinska-Zyrek, Magdalena
    DALTON TRANSACTIONS, 2024, 53 (06) : 2848 - 2858
  • [7] A copper(<sc>ii</sc>)-based metal-organic framework: electrochemical sensing of Cd(<sc>ii</sc>) and Pb(<sc>ii</sc>) and adsorption of organic dyes
    Guo, Ting-Ting
    Hua, Bing-Long
    Guo, Zhuo-Yi
    Zhang, Meng-Qi
    Wang, Jin-Rong
    An, Yan-Yan
    Li, Xiao-Nan
    Yan, Juan-Zhi
    DALTON TRANSACTIONS, 2025, 54 (04) : 1393 - 1401
  • [8] Synthesis, characterization, biological evaluation, DFT and molecular docking studies of (Z)-2-((2-bromo-4-chlorophenyl)imino)methyl)-4-chlorophenol and its Co(<sc>ii</sc>), Ni(<sc>ii</sc>), Cu(<sc>ii</sc>), and Zn(<sc>ii</sc>) complexes
    Waziri, Ibrahim
    Masena, Hlonepho M.
    Yusuf, Tunde L.
    Coetzee, Louis-Charl C.
    Adeyinka, Adedapo S.
    Muller, Alfred J.
    NEW JOURNAL OF CHEMISTRY, 2023, 47 (38) : 17853 - 17870
  • [9] Reduction of nitrite to nitric oxide and generation of reactive chalcogen species by mononuclear Fe(<sc>ii</sc>) and Zn(<sc>ii</sc>) complexes of thiolate and selenolate
    Atta, Sayan
    Mandal, Amit
    Saha, Rahul
    Majumdar, Amit
    DALTON TRANSACTIONS, 2024, 53 (03) : 949 - 965
  • [10] Detailed mechanism of a DNA/RNA nucleobase substituting bridging ligand in diruthenium(<sc>ii</sc>,<sc>iii</sc>) and dirhodium(<sc>ii</sc>,<sc>ii</sc>) tetraacetato paddlewheel complexes: protonation of the leaving acetate is crucial
    Tolbatov, Iogann
    Marzo, Tiziano
    Umari, Paolo
    La Mendola, Diego
    Marrone, Alessandro
    DALTON TRANSACTIONS, 2025, 54 (02) : 662 - 673
12345