Cationic Gemini surfactants: a review on synthesis and their applications

被引:0
|
作者
Naik, Bharti [1 ]
Paranjpe, Susmita S. [1 ]
Madankar, Chandu S. [1 ]
机构
[1] Inst Chem Technol, Dept Oils Oleochem & Surfactants Technol, Mumbai, India
关键词
Gemini surfactants; cationic surfactants; CMC; spacer chain length; ANGLE NEUTRON-SCATTERING; IN-VITRO CYTOTOXICITY; SPACER CHAIN-LENGTH; AGGREGATION PROPERTIES; CHEMICAL HYDROLYSIS; AQUEOUS-SOLUTION; ALKANEDIYL-ALPHA; OMEGA-BIS(DIMETHYLALKYLAMMONIUM BROMIDE); BIOLOGICAL-PROPERTIES; CORROSION-INHIBITORS; ASSISTED SYNTHESIS;
D O I
10.1515/tsd-2024-2585
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The molecules of Gemini surfactants are dimeric and consist of two monomeric surfactant units linked by a spacer. Among them, cationic Gemini surfactants have a wide range of application in various industrial sectors such as pharmaceuticals, home and personal care, corrosion inhibition, etc. Various methods of synthesis have been investigated and tested for the synthesis of cationic Gemini surfactants. The surface properties of Gemini surfactants are highly dependent on various factors like spacer, headgroups, counterions, etc. The cationic Gemini surfactants have lower CMC values as compared to their monomeric analogues. This review highlights the different methods for the synthesis of cationic Gemini surfactants and the applications of these surfactants in different fields are presented.
引用
收藏
页码:491 / 504
页数:14
相关论文
共 50 条
  • [21] Transfection by cationic gemini lipids and surfactants
    Damen, M.
    Groenen, A. J. J.
    van Dongen, S. F. M.
    Nolte, R. J. M.
    Scholte, B. J.
    Feiters, M. C.
    MEDCHEMCOMM, 2018, 9 (09) : 1404 - 1425
  • [22] Novel Cationic Gemini Surfactants and Methods for Determination of Their Antimicrobial Activity - Review
    Tyagi, Shilpa
    Tyagi, Vinod Kumar
    TENSIDE SURFACTANTS DETERGENTS, 2014, 51 (05) : 379 - 386
  • [23] Synthesis and Thermodynamic Properties of Rosin-Based Cationic Gemini Surfactants
    Deng, Weixing
    Zhang, Yongchang
    Zhong, Yuanwei
    Peng, Jinwen
    JOURNAL OF SURFACTANTS AND DETERGENTS, 2014, 17 (03) : 453 - 458
  • [24] Synthesis, surface properties and oil solubilisation capacity of cationic gemini surfactants
    Dam, T
    Engberts, JBFN
    Karthauser, J
    Karaborni, S
    vanOs, NM
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1996, 118 (1-2) : 41 - 49
  • [25] Synthesis and properties of biodegradable cationic gemini surfactants with diester and flexible spacers
    Xu, Dongqing
    Ni, Xiaoyue
    Zhang, Congyu
    Mao, Jie
    Song, Changchun
    JOURNAL OF MOLECULAR LIQUIDS, 2017, 240 : 542 - 548
  • [26] Improved Green Synthesis and Crystal Structures of Symmetrical Cationic Gemini Surfactants
    Singer, Olivia M.
    Campbell, Jacob W.
    Hoare, Jacob G.
    Masuda, Jason D.
    Marangoni, Gerrard
    Singer, Robert D.
    ACS OMEGA, 2022, : 35326 - 35330
  • [27] Synthesis and properties of ester functionalized cationic Gemini surfactants with amide groups
    Lu, Xiaohao
    Xu, Hujun
    Zhou, Yue
    Yao, Tingyi
    Quan, Wang
    Gao, Haiyan
    TENSIDE SURFACTANTS DETERGENTS, 2022, 59 (01) : 51 - 59
  • [28] Synthesis and solution properties of cationic gemini surfactants with long unsaturated tails
    Li, Huazhen
    Yang, Haiyang
    Yan, Yunfei
    Wang, Qin
    He, Pingsheng
    SURFACE SCIENCE, 2010, 604 (13-14) : 1173 - 1178
  • [29] Surface activity research of cationic gemini surfactants
    Fan, Zhenzhong
    Li, Lanlan
    Zhang, Lifeng
    Liu, Qingwang
    ADVANCES IN MATERIALS AND MATERIALS PROCESSING, PTS 1-3, 2013, 652-654 : 1450 - 1454
  • [30] Elongated aggregates formed by cationic gemini surfactants
    Oda, R
    Huc, I
    Homo, JC
    Heinrich, B
    Schmutz, M
    Candau, S
    LANGMUIR, 1999, 15 (07) : 2384 - 2390