Cationic Gemini surfactants: a review on synthesis and their applications

被引：1

作者：

Naik, Bharti ^{[1
]}

Paranjpe, Susmita S. ^{[1
]}

Madankar, Chandu S. ^{[1
]}

机构：

[1] Inst Chem Technol, Dept Oils Oleochem & Surfactants Technol, Mumbai, India

来源：

TENSIDE SURFACTANTS DETERGENTS | 2024年 / 61卷 / 05期

关键词：

Gemini surfactants; cationic surfactants; CMC; spacer chain length; ANGLE NEUTRON-SCATTERING; IN-VITRO CYTOTOXICITY; SPACER CHAIN-LENGTH; AGGREGATION PROPERTIES; CHEMICAL HYDROLYSIS; AQUEOUS-SOLUTION; ALKANEDIYL-ALPHA; OMEGA-BIS(DIMETHYLALKYLAMMONIUM BROMIDE); BIOLOGICAL-PROPERTIES; CORROSION-INHIBITORS; ASSISTED SYNTHESIS;

D O I：

10.1515/tsd-2024-2585

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The molecules of Gemini surfactants are dimeric and consist of two monomeric surfactant units linked by a spacer. Among them, cationic Gemini surfactants have a wide range of application in various industrial sectors such as pharmaceuticals, home and personal care, corrosion inhibition, etc. Various methods of synthesis have been investigated and tested for the synthesis of cationic Gemini surfactants. The surface properties of Gemini surfactants are highly dependent on various factors like spacer, headgroups, counterions, etc. The cationic Gemini surfactants have lower CMC values as compared to their monomeric analogues. This review highlights the different methods for the synthesis of cationic Gemini surfactants and the applications of these surfactants in different fields are presented.

引用

页码：491 / 504

页数：14

共 90 条

[1] Cationic gemini surfactants containing biphenyl spacer as shale swelling inhibitor [J].

Ahmad, Hafiz Mudaser ;

Murtaza, Mobeen ;

Kamal, Muhammad Shahzad ;

Hussain, S. M. Shakil ;

Mahmoud, Mohamed .

JOURNAL OF MOLECULAR LIQUIDS, 2021, 325

[2] Cationic gemini surfactant properties, its potential as a promising bioapplication candidate, and strategies for improving its biocompatibility: A review [J].

Ahmady, Azin Rashidy ;

Hosseinzadeh, Pakshid ;

Solouk, Atefeh ;

Akbari, Somaye ;

Szulc, Adrianna M. ;

Brycki, Bogumil E. .

ADVANCES IN COLLOID AND INTERFACE SCIENCE, 2022, 299

[3] Biophysical investigation of the interaction between NSAID ibuprofen and cationic biodegradable Cm-E2O2-Cm gemini surfactants [J].

Akram, Mohd. ;

Osama, Mohammad ;

Lal, Hira ;

Salim, Mohammad ;

Hashmi, Md Amiruddin ;

Din, Kabir-ud .

JOURNAL OF MOLECULAR LIQUIDS, 2023, 370

[4] An Insight View on Synthetic Protocol, Surface Activity, and Biological Aspects of Novel Biocompatible Quaternary Ammonium Cationic Gemini Surfactants [J].

Akram, Mohd ;

Lal, Hira ;

Osama, Mohammad ;

Ansari, Farah ;

Anwar, Sana ;

Kabir-ud-Din ;

Ahmad, Ajaz ;

Samreen ;

Azum, Naved ;

Marwani, Hadi M. ;

Asiri, Abdullah M. .

JOURNAL OF SURFACTANTS AND DETERGENTS, 2021, 24 (01) :35-49

[5] Aggregation behavior and intermicellar interactions of cationic Gemini surfactants: Effects of alkyl chain, spacer lengths and temperature [J].

Alimohammadi, Marjan Hajy ;

Javadian, Soheila ;

Gharibi, Hussein ;

Tehrani-Bagha, Ali Reza ;

Alavijeh, Mohammad Rashidi ;

Kakaei, Karim .

JOURNAL OF CHEMICAL THERMODYNAMICS, 2012, 44 (01) :107-115

[6] Self-organization at the interface and in aqueous solution of a cationic gemini surfactant from the dioctyl ester of cystine [J].

Angayarkanny, S. ;

Vijay, R. ;

Baskar, Geetha ;

Mandal, A. B. .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2012, 367 :319-326

[7] Small-angle neutron scattering study of micellar structures of dimeric surfactants [J].

Aswal, VK ;

De, S ;

Goyal, PS ;

Bhattacharya, S ;

Heenan, RK .

PHYSICAL REVIEW E, 1998, 57 (01) :776-783

[8]

Atzrodt J, 2017, ANGEW CHEM INT EDIT, P1, DOI [10.1002/anie.201704146, DOI 10.1002/ANIE.201704146]

[9] Assessment of primary eye and skin irritants by in vitro cytotoxicity and phototoxicity models:: an in vitro approach of new arginine-based surfactant-induced irritation [J].

Benavides, T ;

Mitjans, M ;

Martínez, A ;

Clapés, P ;

Infante, MR ;

Clothier, RH ;

Vinardell, MP .

TOXICOLOGY, 2004, 197 (03) :229-237

[10] Novel Gemini Pyridinium Surfactants: Synthesis and Study of Their Surface Activity, DNA Binding, and Cytotoxicity [J].

Bhadani, Avinash ;

Singh, Sukhprit .

LANGMUIR, 2009, 25 (19) :11703-11712

← 1 2 3 4 5 6 7 8 9 →