Three-dimensional simulation of alkaline electrolyzer with an advanced partitioned point flow channel

被引:2
作者
Liang, Huan [1 ]
Lin, Saisai [1 ]
Zhao, Ke [1 ]
Liu, Peng [1 ]
Hu, Nan [1 ]
Song, Hao [1 ]
Yang, Yang [1 ,2 ]
Zheng, Chenghang [1 ,2 ,3 ]
Zhang, Xiao [1 ,2 ,3 ]
Gao, Xiang [1 ,2 ,3 ]
机构
[1] Zhejiang Univ, State Environm Protect Ctr Coal Fired Air Pollut C, State Key Lab Clean Energy Utilizat, Hangzhou 310027, Peoples R China
[2] Zhejiang Univ, Jiaxing Res Inst, Key Lab Clean Energy & Carbon Neutral Zhejiang Pro, Jiaxing 314000, Peoples R China
[3] Baima Lake Lab, Hangzhou 310051, Peoples R China
基金
中国国家自然科学基金;
关键词
Alkaline electrolyzer; Electrochemistry; Flow channel design; Mass and heat transfer; Flow uniformity; PEM WATER ELECTROLYSIS; HYDROGEN EVOLUTION; BUBBLE COVERAGE; FIELD; EFFICIENCY; HYDRODYNAMICS; TEMPERATURE; PERFORMANCE; ANODE;
D O I
10.1016/j.ijhydene.2024.09.015
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Alkaline water electrolysis (AWE) holds considerable promise for large-scale hydrogen production. Decreasing energy input and improving efficiency are inevitable in its further commercial development. As one of the critical factors for reducing energy consumption, flow channel design on bipolar plates cannot be ignored. This study utilizes a three-dimensional model for alkaline electrolyzer that couples electrochemical reactions with mass and heat transfer to approximate the real physical process and achieve reliable convergence. Integrating diverse turbulence units tailored to different local flow demands, an advanced Partitioned Point Flow Channel (PPFC) structure is proposed aiming at optimizing electrolyte flow distribution. Results reveal that PPFC's unique combination of turbulence units promotes lateral flow and electrolyte mass transfer rate, increasing electrolyte flow uniformity and hydrogen removal efficiency by 17.5% and 24.4%, respectively. Further comparative analysis with traditional designs shows an average diaphragm temperature drop of 4 K and a current density increase of 10.7% at a cell voltage of 2 V. These results indicate that PPFC offers significant advantages in reducing energy loss in electrolyzer.
引用
收藏
页码:1252 / 1261
页数:10
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