Hydrothermally Synthesized rGO/MnO2/MoS2 Nanohybrids as Superior Bifunctional Electrocatalysts for Oxygen and Hydrogen Evolution Reactions

被引:0
作者
Denisdon, Simiyon [1 ,2 ]
Kumar, Ponnusamy Senthil [4 ]
Boobalan, Chitra [1 ,2 ]
Rangasamy, Gayathri [3 ]
机构
[1] Sri Sivasubramaniya Nadar Coll Engn, Dept Chem Engn, Kalavakkam 603110, Tamil Nadu, India
[2] Sri Sivasubramaniya Nadar Coll Engn, Ctr Excellence Water Res CEWAR, Kalavakkam 603110, Tamil Nadu, India
[3] Karpagam Acad Higher Educ, Fac Engn, Dept Civil Engn, Coimbatore 641021, Tamil Nadu, India
[4] Pondicherry Univ, Ctr Pollut Control & Environm Engn, Sch Engn & Technol, Kalapet 605014, Puducherry, India
关键词
OPTICAL-PROPERTIES; PERFORMANCE; ELECTRODE; GRAPHENE; CO; NANOCOMPOSITE; NANOSHEETS; COMPOSITE; CATALYSTS;
D O I
10.1021/acs.langmuir.4c02192
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This investigation delved into the field of bifunctional electrocatalyst water splitting, aimed at advancing sustainable energy by addressing the scarcity of efficient nonprecious electrocatalysts capable of facilitating both the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER). This study focused on nanohybrids consisting of hydrothermally synthesized rGO/MnO2/MoS2 composites and highlighted their efficacy as bifunctional electrocatalysts. The synergistic integration of rGO/MnO2/MoS2 enhanced the surface area, magnified electroactive sites, established a customized conductive arrangement, and provoked the efficiency in splitting of water. The nanohybrid displayed exceptional catalytic performance for the OER and HER, with significantly reduced overpotentials of 208 and 205 mV in 1 M KOH at 10 mA cm(-2) current density, respectively. The findings underscore the potential of these cost-effective and environmentally friendly rGO/MnO2/MoS2 nanohybrids in advancing the field of electrocatalysis for renewable energy applications.
引用
收藏
页码:17753 / 17766
页数:14
相关论文
共 63 条
  • [1] Electrochemistry of Graphene and Related Materials
    Ambrosi, Adriano
    Chua, Chun Kiang
    Bonanni, Alessandra
    Pumera, Martin
    [J]. CHEMICAL REVIEWS, 2014, 114 (14) : 7150 - 7188
  • [2] Epitaxial Heterogeneous Interfaces on N-NiMoO4/NiS2 Nanowires/Nanosheets to Boost Hydrogen and Oxygen Production for Overall Water Splitting
    An, Li
    Feng, Jianrui
    Zhang, Yu
    Wang, Rui
    Liu, Hanwen
    Wang, Gui-Chang
    Cheng, Fangyi
    Xi, Pinxian
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2019, 29 (01)
  • [3] MoS2/NiSe2/rGO Multiple-Interfaced Sandwich-like Nanostructures as Efficient Electrocatalysts for Overall Water Splitting
    Bai, Xiaoyan
    Cao, Tianqi
    Xia, Tianyu
    Wu, Chenxiao
    Feng, Menglin
    Li, Xinru
    Mei, Ziqing
    Gao, Han
    Huo, Dongyu
    Ren, Xiaoyan
    Li, Shunfang
    Guo, Haizhong
    Wang, Rongming
    [J]. NANOMATERIALS, 2023, 13 (04)
  • [4] NiCo2O4 nano-needles as an efficient electro-catalyst for simultaneous water splitting and dye degradation
    Bilal, Muhammad
    Altaf, Amna
    Bint-E-Khalid, Ehmen
    Zafar, Hafiza Komal
    Tahir, Nimrah
    Nafady, Ayman
    Wahab, Md A.
    Shah, Syed Shoaib Ahmad
    Najam, Tayyaba
    Sohail, Manzar
    [J]. RSC ADVANCES, 2023, 13 (34) : 23547 - 23557
  • [5] Optimization of active surface area of flower like MoS2 using V-doping towards enhanced hydrogen evolution reaction in acidic and basic medium
    Bolar, Saikat
    Shit, Subhasis
    Kumar, J. Sharath
    Murmu, Naresh Chandra
    Ganesh, R. Sankar
    Inokawa, Hiroshi
    Kuila, Tapas
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2019, 254 : 432 - 442
  • [6] Manganese oxide thin film preparation by potentiostatic electrolyses and electrochromism
    Chigane, M
    Ishikawa, M
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (06) : 2246 - 2251
  • [7] Reduced graphene oxide-based materials for electrochemical energy conversion reactions
    Choi, Seokhoon
    Kim, Changyeon
    Suh, Jun Min
    Jang, Ho Won
    [J]. CARBON ENERGY, 2019, 1 (01) : 85 - 108
  • [8] Marigold shaped N-rGO-MoS2-Ni(OH)2 nanocomposite as a bifunctional electrocatalyst for the promotion of overall water splitting in alkaline medium
    Debata, Suryakanti
    Banerjee, Sanchari
    Sharma, Prashant K.
    [J]. ELECTROCHIMICA ACTA, 2019, 303 : 257 - 267
  • [9] Hierarchical Co and Nb dual-doped MoS2 nanosheets shelled micro-TiO2 hollow spheres as effective multifunctional electrocatalysts for HER, OER, and ORR
    Dinh Chuong Nguyen
    Thi Luu Luyen Doan
    Prabhakaran, Sampath
    Duy Thanh Tran
    Kim, Do Hwan
    Lee, Joong Hee
    Kim, Nam Hoon
    [J]. NANO ENERGY, 2021, 82
  • [10] Surface-Guided Formation of Amorphous Mixed-Metal Oxyhydroxides on Ultrathin MnO2 Nanosheet Arrays for Efficient Electrocatalytic Oxygen Evolution
    Fang, Ming
    Han, Dong
    Xu, Wen-Bo
    Shen, Yun
    Lu, Youming
    Cao, Peijiang
    Han, Shun
    Xu, Wangying
    Zhu, Deliang
    Liu, Wenjun
    Ho, Johnny C.
    [J]. ADVANCED ENERGY MATERIALS, 2020, 10 (27)