Controllable Design of Polyamide Composite Membrane Separation Layer Structures via Metal-Organic Frameworks: A Review

被引：1
作者：
Jia, Yanjun [1 ]
Huo, Xiaowen [2 ]
Gao, Lu [2 ]
Shao, Wei [3 ,4 ]
Chang, Na [2 ,3 ,4 ]
机构：
[1] Tiangong Univ, Sch Environm Sci & Engn, Tianjin 300387, Peoples R China
[2] Tiangong Univ, Sch Text Sci & Engn, Tianjin 300387, Peoples R China
[3] Tiangong Univ, Sch Chem Engn & Technol, Tianjin 300387, Peoples R China
[4] State Key Lab Separat Membranes & Membrane Proc, Tianjin 300387, Peoples R China
来源：
MEMBRANES | 2024年 / 14卷 / 09期
基金：
国家重点研发计划;
关键词：
metal-organic framework; thin-film nanocomposite; membrane; reverse osmosis; nanofiltration; FILM NANOCOMPOSITE MEMBRANES; NANOFILTRATION MEMBRANE; COORDINATION POLYMER; PERFORMANCE; SIZE; FABRICATION; MODULATION; NANOSHEETS; NANOFILMS; TRANSPORT;
D O I：
10.3390/membranes14090201
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Optimizing the structure of the polyamide (PA) layer to improve the separation performance of PA thin-film composite (TFC) membranes has always been a hot topic in the field of membrane preparation. As novel crystalline materials with high porosity, multi-functional groups, and good compatibility with membrane substrate, metal-organic frameworks (MOFs) have been introduced in the past decade for the modification of the PA structure in order to break through the separation trade-off between permeability and selectivity. This review begins by summarizing the recent progress in the control of MOF-based thin-film nanocomposite (TFN) membrane structures. The review also covers different strategies used for preparing TFN membranes. Additionally, it discusses the mechanisms behind how these strategies regulate the structure and properties of PA. Finally, the design of a competent MOF material that is suitable to reach the requirements for the fabrication of TFN membranes is also discussed. The aim of this paper is to provide key insights into the precise control of TFN-PA structures based on MOFs.
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页数：28
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