Sr(Cr0.2Mn0.2Fe0.2Co0.2Ni0.2)O3: A novel high-entropy perovskite oxide with enhanced electromagnetic wave absorption properties

被引:23
作者
Li, Mengru [1 ]
Zhi, Qing [1 ]
Li, Jinlu [1 ]
Wu, Chengwen [1 ]
Jiang, Xuewen [1 ]
Min, Zhiyu [2 ]
Zhang, Rui [1 ,3 ]
Wang, Hailong [1 ]
Wang, Haibin [3 ]
Fan, Bingbing [1 ]
机构
[1] Zhengzhou Univ, Sch Mat Sci & Engn, Zhengzhou 450001, Peoples R China
[2] Luoyang Inst Sci & Technol, Sch Mat Sci & Engn, Luoyang 471023, Henan, Peoples R China
[3] Henan Acad Sci, Inst Adv Ceram, Zhengzhou 450046, Peoples R China
基金
中国国家自然科学基金;
关键词
High-entropy ceramics; Perovskite; Microwave absorption; Magnetism; RARE-EARTH; MICROWAVE-ABSORPTION;
D O I
10.1016/j.jmat.2023.11.019
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Perovskite materials (ABO3) 3 ) possess a wealth of elements selectable and exhibit a diverse range of octahedral transformations. The emergence of high-entropy perovskite ceramics provides a fresh perspective for advancing the field of wave-absorbing materials. In this study, we concentrate on the wet chemical synthesis of a high-entropy perovskite oxide, Sr(Cr0.2Mn0.2Fe0.2Co0.2Ni0.2)O3, 0.2 Mn 0.2 Fe 0.2 Co 0.2 Ni 0.2 )O 3 , and investigate its crystal structure, microstructure, chemical composition, magnetic properties, and microwave absorbing capabilities. The results indicate that when sintered at a temperature of 1,350 degrees C, the sample achieves a minimum reflection loss of- 54.0 dB at a frequency of 9.68 GHz, accompanied by a maximum effective absorption bandwidth (EAB) of 7.44 GHz at the thickness of 1.8 mm. The high-entropy design of the Bsite induces distortions of oxygen vacancy and octahedral structure of the perovskite material. This leads to the fine tuning of its dielectric and magnetic properties, thereby endowing perovskite with excellent electromagnetic wave absorption capabilities. Consequently, perovskite emerges as a promising new electromagnetic wave absorption material with significant potential. (c) 2023 Published by Elsevier B.V. on behalf of The Chinese Ceramic Society. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
引用
收藏
页码:1176 / 1185
页数:10
相关论文
共 58 条
[1]   High-Entropy Perovskites: An Emergent Class of Oxide Thermoelectrics with Ultralow Thermal Conductivity [J].
Banerjee, Ritwik ;
Chatterjee, Sabitabrata ;
Ranjan, Mani ;
Bhattacharya, Tathagata ;
Mukherjee, Soham ;
Jana, Subhra Sourav ;
Dwivedi, Akansha ;
Maiti, Tanmoy .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2020, 8 (46) :17022-17032
[2]   Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni [J].
Biesinger, Mark C. ;
Payne, Brad P. ;
Grosvenor, Andrew P. ;
Lau, Leo W. M. ;
Gerson, Andrea R. ;
Smart, Roger St. C. .
APPLIED SURFACE SCIENCE, 2011, 257 (07) :2717-2730
[3]   What is in a name: Defining "high entropy" oxides [J].
Brahlek, Matthew ;
Gazda, Maria ;
Keppens, Veerle ;
Mazza, Alessandro R. ;
McCormack, Scott J. ;
Mielewczyk-Gryn, Aleksandra ;
Musico, Brianna ;
Page, Katharine ;
Rost, Christina M. ;
Sinnott, Susan B. ;
Toher, Cormac ;
Ward, Thomas Z. ;
Yamamoto, Ayako .
APL MATERIALS, 2022, 10 (11)
[4]   Genetic Dielectric Genes Inside 2D Carbon-Based Materials with Tunable Electromagnetic Function at Elevated Temperature [J].
Cao, Mao-Sheng ;
Shu, Jin-Cheng ;
Wen, Bo ;
Wang, Xi-Xi ;
Cao, Wen-Qiang .
SMALL STRUCTURES, 2021, 2 (11)
[5]   Achieving strong microwave absorption capability and wide absorption bandwidth through a combination of high entropy rare earth silicide carbides/rare earth oxides [J].
Chen, Heng ;
Zhao, Biao ;
Zhao, Zifan ;
Xiang, Huimin ;
Dai, Fu-Zhi ;
Liu, Jiachen ;
Zhou, Yanchun .
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY, 2020, 47 :216-222
[6]   Multiprincipal Element M2FeC (M = Ti,V,Nb,Ta,Zr) MAX Phases with Synergistic Effect of Dielectric and Magnetic Loss [J].
Chen, Lu ;
Li, Youbing ;
Zhao, Biao ;
Liu, Shanshan ;
Zhang, Huibin ;
Chen, Ke ;
Li, Mian ;
Du, Shiyu ;
Xiu, Faxian ;
Che, Renchao ;
Chai, Zhifang ;
Huang, Qing .
ADVANCED SCIENCE, 2023, 10 (10)
[7]   Research progress on nanostructure design and composition regulation of carbon spheres for the microwave absorption [J].
Chen, Xinting ;
Wu, Yue ;
Gu, Weihua ;
Zhou, Ming ;
Tang, Shaolong ;
Cao, Jieming ;
Zou, Zhongqiu ;
Ji, Guangbin .
CARBON, 2022, 189 :617-633
[8]   Preparation and dielectric properties of lead-free perovskite-structured high-entropy ceramics of (La0.25Sr0.25Ba0.25Na0.25)(Ti0.5Me0.5)O3-δ (Me=Sn, Zr, Hf) via doping at both A and B sites [J].
Chen, Yingquan ;
Li, Rui ;
Zhang, Yan ;
Long, Yanping ;
Liu, Na ;
Xia, Haijun ;
Luo, Xiong ;
Meng, Bin .
CERAMICS INTERNATIONAL, 2023, 49 (01) :1038-1047
[9]   Quantitative Evaluation of Loss Capability for In Situ Conductive Phase Enhanced Microwave Absorption of High-Entropy Transition Metal Oxides [J].
Dai, Guohao ;
Deng, Ruixiang ;
Zhang, Tao ;
Yu, Yun ;
Song, Lixin .
ADVANCED FUNCTIONAL MATERIALS, 2022, 32 (35)
[10]   Entropy-driven phase regulation of high-entropy transition metal oxide and its enhanced high-temperature microwave absorption by in-situ dual phases [J].
Dai, Guohao ;
Deng, Ruixiang ;
You, Xiao ;
Zhang, Tao ;
Yu, Yun ;
Song, Lixin .
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY, 2022, 116 :11-21