Zirconium and cerium dioxide fabricated activated carbon-based nanocomposites for enhanced adsorption and photocatalytic removal of methylene blue and tetracycline hydrochloride

Activated carbon (AC) is a porous, amorphous form of carbon known for its strong adsorption capacity, making it highly effective for use in wastewater treatment. In this investigation, AC-based nanocomposites (NCs) loaded with zirconium dioxide and cerium dioxide nanoparticles (ZrO2/CeO2 NPs) were successfully synthesized for the effective elimination of methylene blue (MB) and tetracycline hydrochloride (TCH). The AC-ZrO2/CeO2 NCs have a size of 231.83 nm, a zeta potential of -20.07 mV, and a PDI value of 0.160. The adsorption capacities of AC-ZrO2/CeO2 NCs for MB and TCH were proved in agreement with the Langmuir isotherm and pseudo 1st order kinetic model, respectively. The maximum adsorption capacities were determined to be 75.54 mg/g for MB and 26.75 mg/g for TCH. Notably, AC-ZrO2/CeO2 NCs exhibited superior photocatalytic degradation efficiency for MB and TCH under sunlight irradiation with removal efficiencies reaching up to 97.91% and 82.40% within 90 min, respectively. The t1/2 for the photo-degradation process of MB and TCH were 11.55 min and 44.37 min. Analysis of active species trapping confirmed the involvement of hole (h+), superoxide anion (center dot O2- ), and hydroxyl radical (center dot OH) in the degradation mechanism. Furthermore, the residual solution post-contaminant removal exhibited minimal toxicity towards Artemia salina and NIH3T3 cells. Importantly, the NCs did not exhibit antibacterial activity against tested pathogens post-absorption/degradation of TCH. Thus, AC-ZrO2/CeO2 NCs could be a promising nanomaterial for wastewater treatment applications.