Highly Efficient, Iodine-Free Dye-Sensitized Solar Cells with Solid-State Synthesis of Conducting Polymers

被引:183
作者
Koh, Jong Kwan [1 ]
Kim, Jeonghun [1 ]
Kim, Byeonggwan [1 ]
Kim, Jong Hak [1 ]
Kim, Eunkyoung [1 ]
机构
[1] Yonsei Univ, Dept Chem & Biomol Engn, Seoul 120749, South Korea
关键词
TITANIUM-DIOXIDE FILMS; CHARGE RECOMBINATION; HOLE CONDUCTORS; MESOPOROUS TIO2; NANOCRYSTALLINE; POLY(3,4-ETHYLENEDIOXYTHIOPHENE); ELECTROLYTE; KINETICS; ANIONS; OXIDE;
D O I
10.1002/adma.201004715
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A solid-state polymerizable conductive monomer with good conductivity and penetration to the photoelectrode is introduced to iodine-free, solid-state dye-sensitized solar cells (DSSCs) using an easily accessible and widely applicable fabrication method. A conducting polymer as a hole transporting material effectively penetrates into the TiO2 pores and polymerizes with heating to mild temperatures. The fabricated DSSCs exhibited the highest energy conversion efficiency of 5.4% in N719 dye.
引用
收藏
页码:1641 / +
页数:7
相关论文
共 40 条
[11]   Interface engineering for solid-state dye-sensitized nanocrystalline solar cells: The use of ion-solvating hole-transporting polymers [J].
Haque, SA ;
Park, T ;
Xu, C ;
Koops, S ;
Schulte, N ;
Potter, RJ ;
Holmes, AB ;
Durrant, JR .
ADVANCED FUNCTIONAL MATERIALS, 2004, 14 (05) :435-440
[12]   Charge recombination kinetics in dye-sensitized nanocrystalline titanium dioxide films under externally applied bias [J].
Haque, SA ;
Tachibana, Y ;
Klug, DR ;
Durrant, JR .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (10) :1745-1749
[13]   A high performance dye-sensitized solar cell with a novel nanocomposite film of PtNP/MWCNT on the counter electrode [J].
Huang, Kuan-Chieh ;
Wang, Ying-Chiao ;
Dong, Rui-Xuan ;
Tsai, Wei-Cheng ;
Tsai, Keng-Wei ;
Wang, Chun-Chieh ;
Chen, You-Han ;
Vittal, R. ;
Lin, Jiang-Jen ;
Ho, Kuo-Chuan .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (20) :4067-4073
[14]   Photovoltaics Based on Hybridization of Effective Dye-Sensitized Titanium Oxide and Hole-Conductive Polymer P3HT [J].
Jiang, Ke-Jian ;
Manseki, Kazuhiro ;
Yu, You-Hai ;
Masaki, Naruhiko ;
Suzuki, Kazuharu ;
Song, Yan-lin ;
Yanagida, Shozo .
ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (15) :2481-2485
[15]   Oligomer approaches for solid-state dye-sensitized solar cells employing polymer electrolytes [J].
Kang, Moon-Sung ;
Kim, Jong Hak ;
Won, Jongok ;
Kang, Yong Soo .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (13) :5222-5228
[16]   Flexible Conductive Polymer Patterns from Vapor Polymerizable and Photo-Cross-Linkable EDOT [J].
Kim, Jeonghun ;
You, Jungmok ;
Kim, Eunkyoung .
MACROMOLECULES, 2010, 43 (05) :2322-2327
[17]   Azide-induced crosslinking of electrolytes and its application in solid-state dye-sensitized solar cells [J].
Koh, Joo Hwan ;
Koh, Jong Kwan ;
Park, Nam-Gyu ;
Kim, Jong Hak .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2010, 94 (03) :436-441
[18]   Dye-sensitized solid-state solar cells made from magnesiumoxide-coated nanocrystalline titanium dioxide films: enhancement of the efficiency [J].
Kumara, GRA ;
Okuya, M ;
Murakami, K ;
Kaneko, S ;
Jayaweera, VV ;
Tennakone, K .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 164 (1-3) :183-185
[19]   Iodine-free high efficient quasi solid-state dye-sensitized solar cell containing ionic liquid and polyaniline-loaded carbon black [J].
Lee, Chuan-Pei ;
Chen, Po-Yen ;
Vittal, R. ;
Ho, Kuo-Chuan .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (12) :2356-2361
[20]   Surface Passivation of Nanoporous TiO2 via Atomic Layer Deposition of ZrO2 for Solid-State Dye-Sensitized Solar Cell Applications [J].
Li, Tina C. ;
Goes, Marcio S. ;
Fabregat-Santiago, Francisco ;
Bisquert, Juan ;
Bueno, Paulo R. ;
Prasittichai, Chaiya ;
Hupp, Joseph T. ;
Marks, Tobin J. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (42) :18385-18390