Highly Efficient, Iodine-Free Dye-Sensitized Solar Cells with Solid-State Synthesis of Conducting Polymers

被引:183
作者
Koh, Jong Kwan [1 ]
Kim, Jeonghun [1 ]
Kim, Byeonggwan [1 ]
Kim, Jong Hak [1 ]
Kim, Eunkyoung [1 ]
机构
[1] Yonsei Univ, Dept Chem & Biomol Engn, Seoul 120749, South Korea
关键词
TITANIUM-DIOXIDE FILMS; CHARGE RECOMBINATION; HOLE CONDUCTORS; MESOPOROUS TIO2; NANOCRYSTALLINE; POLY(3,4-ETHYLENEDIOXYTHIOPHENE); ELECTROLYTE; KINETICS; ANIONS; OXIDE;
D O I
10.1002/adma.201004715
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A solid-state polymerizable conductive monomer with good conductivity and penetration to the photoelectrode is introduced to iodine-free, solid-state dye-sensitized solar cells (DSSCs) using an easily accessible and widely applicable fabrication method. A conducting polymer as a hole transporting material effectively penetrates into the TiO2 pores and polymerizes with heating to mild temperatures. The fabricated DSSCs exhibited the highest energy conversion efficiency of 5.4% in N719 dye.
引用
收藏
页码:1641 / +
页数:7
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