2-{(E)-{{(R)-1-[(1R,5S,6R)-3,3-Dimethyl-2,4,7-trioxabicyclo[3.3.0]octan-6-yl]ethyl}imino}methyl}-6-{[(diphenylphosphino)oxy] phenyl}palladium(II) chloride

被引：0

作者：

Guillarme, Stephane ^{[1
]}

Saluzzo, Christine ^{[1
]}

机构：

[1] Le Mans Univ, Inst Mol & Materiaux Mans IMMM, MSO, CNRS ,UMR 6283, Ave O Messiaen, F-72085 Le Mans 9, France

来源：

MOLBANK | 2024年 / 2024卷 / 02期

关键词：

isosorbide; isohexide; optical active PCN pincer palladium(II) complex; phosphinite; imine; sustainable material; PINCER COMPLEXES; PLATINUM; ISOHEXIDES; CATALYSIS; PALLADIUM; VERSATILE; LIGANDS;

D O I：

10.3390/M1838

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An unsymmetrical PCN palladium pincer complex 2-{(E)-{{(R)-1-[(1R,5S,6R)-3,3-dimethyl-2,4,7-trioxabicyclo[3.3.0]octan-6-yl]ethyl}imino}methyl}-6-{[(diphenylphosphino)oxy] phenyl}palladium(II) chloride based on an iminophosphinite ligand bearing two fused five-membered cycles, one of which containing a THF ring, was prepared in an eight-reaction sequence from a sustainable and enantiopure starting material, isosorbide, in a 20% overall yield.

引用

页数：5