2-{(E)-{{(R)-1-[(1R,5S,6R)-3,3-Dimethyl-2,4,7-trioxabicyclo[3.3.0]octan-6-yl]ethyl}imino}methyl}-6-{[(diphenylphosphino)oxy] phenyl}palladium(II) chloride

被引：0

作者：

Guillarme, Stephane ^{[1
]}

Saluzzo, Christine ^{[1
]}

机构：

[1] Le Mans Univ, Inst Mol & Materiaux Mans IMMM, MSO, CNRS ,UMR 6283, Ave O Messiaen, F-72085 Le Mans 9, France

来源：

MOLBANK | 2024年 / 2024卷 / 02期

关键词：

isosorbide; isohexide; optical active PCN pincer palladium(II) complex; phosphinite; imine; sustainable material; PINCER COMPLEXES; PLATINUM; ISOHEXIDES; CATALYSIS; PALLADIUM; VERSATILE; LIGANDS;

D O I：

10.3390/M1838

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An unsymmetrical PCN palladium pincer complex 2-{(E)-{{(R)-1-[(1R,5S,6R)-3,3-dimethyl-2,4,7-trioxabicyclo[3.3.0]octan-6-yl]ethyl}imino}methyl}-6-{[(diphenylphosphino)oxy] phenyl}palladium(II) chloride based on an iminophosphinite ligand bearing two fused five-membered cycles, one of which containing a THF ring, was prepared in an eight-reaction sequence from a sustainable and enantiopure starting material, isosorbide, in a 20% overall yield.

引用

页数：5

共 3 条

[1] Synthesis of carbasugars from aldonolactones, part III -: A study on the allylic substitution of (1R,5R,8R)- and (1R,5R,8S)-8-hydroxy-2-oxabicyclo[3.3.0]oct-6-en-3-one derivatives -: Preparation of (1S,2R,3R)-9-[2-hydroxy-3-(2-hydroxyethyl)cyclopent-4-en-1-yl]-9H-adenine
Johansen, SK
Lundt, I
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2001, 2001 (06) : 1129 - 1136
[2] Synthesis and Molecular Structure of N-{(1R,5S)-3-Methyl-8-Oxo-1,3,4,5,6,8-Hexahydro-2H-1,5-Methanopyrido[1,2-α] [1,5]Diazocin-9-yl}Acetamide
Suponitskii, K. Yu.
Koval'skaya, A. V.
Tsypysheva, I. P.
CHEMISTRY OF NATURAL COMPOUNDS, 2014, 50 (03) : 581 - 582
[3] The 5(S)-((3aR,4R,6aR)-2,2-Dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl)-2-phenyl-4,5-dihydrooxazole
Boiaryna, Liliana
Guillarme, Stephane
Saluzzo, Christine
MOLBANK, 2024, 2024 (03)

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