CuSO4/N-(9H-carbazol-9-yl)picolinamide-Catalyzed C-O Coupling of (Hetero)Aryl Chlorides with Phenols on Water

被引：4

作者：

Hong, Peng ^{[1
,2
]}

Zhu, Xinhai ^{[2
,3
]}

Chen, Fu ^{[1
]}

Huang, Manna ^{[1
,2
]}

Wan, Yiqian ^{[1
,2
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem Engn & Technol, Zhuhai 519082, Peoples R China

[2] Sun Yat Sen Univ, Guangdong Engn Technol Res Ctr Platform Chem Marin, Zhuhai 519082, Peoples R China

[3] Sun Yat Sen Univ, Instrument Anal & Res Ctr, Guangzhou 510275, Peoples R China

来源：

ORGANIC LETTERS | 2024年 / 26卷 / 34期

基金：

中国国家自然科学基金;

关键词：

DIARYL ETHERS; ARYL HALIDES; CATALYZED ARYLATION; LIGAND; BOND; SUBSTITUTION;

D O I：

10.1021/acs.orglett.4c02620

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Cu-catalyzed C-O coupling of (hetero)aryl chlorides with phenols at 120 degrees C on water was developed with a designed ligand, N-(9H-carbazol-9-yl)picolinamide (L2). This method features a good substrate scope (both electron-donating and electron-withdrawing), low catalyst/ligand loadings (down to 1 mol %), and excellent scalability and practicability.

引用

页码：7202 / 7206

页数：5

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