Preparation and sodium storage properties of CoFe2O4 composite S N co-doped RGO

被引:1
作者
Zhao, Tianqing [1 ]
Li, Qi [1 ]
Jiang, Wenquan [2 ]
Qiu, Hengrui [1 ]
Zhang, Yongqiang [1 ]
He, Wenxiu [1 ]
机构
[1] Inner Mongolia Univ Sci & Technol, Sch Chem & Chem Engn, Baotou 014010, Inner Mongolia, Peoples R China
[2] Grimat Engn Inst Co Ltd, Beijing 100088, Peoples R China
关键词
Sodium ion battery; Negative electrode; Graphene; Element doping; Electrochemical performance; CoFe2O4; PERFORMANCE ANODE MATERIALS; REDUCED GRAPHENE OXIDE; CARBON NANOFIBERS; LITHIUM; NANOCOMPOSITES; NANOSHEETS; FE2O3;
D O I
10.1016/j.jallcom.2024.176411
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The application value of iron-base binary oxide in sodium-ion batteries has been widely concerned by researchers, and CoFe2O4 has a better development prospect because of its cost efficiency. However, the CoFe2O4 will produce volume expansion during the reaction, resulting in the collapse of the material structure. This paper created the ground-breaking CFO/SNRGO nanocomposite structure by using a microwave approach. This intricate arrangement entails CoFe2O4 nanoparticles firmly adhering to S and N co-doped graphene hybrid nanosheets. The prepared CFO/SNRGO nanocomposite showcased remarkable electrochemical capabilities. Through the uniform integration of CoFe2O4 nanoparticles onto the SNRGO hybrid nanosheets, we managed to minimize the stacking between SNRGO nanosheets and reduce the size of the CoFe2O4 nanoparticles. Additionally, the SNRGO serves as a buffer layer, allowing it to adjust to variations in volume and stop the CoFe2O4 nanoparticles from collapsing while Na+ is being embedded or removed. This cooperative amalgamation of SNRGO and CoFe2O4 contributes to the outstanding electrochemical performance observed in the CFO/SNRGO nanocomposites. After 200 cycles at an electrical concentration of 0.05 A g(-1), the CFO/SNRGO nanotechnology demonstrated a notable 357.3 mAh g(-1) bidirectional ability. and sustained excellent rate performance. Even when subjected to an increased electrical concentration of 1.5 A g(-1), the reversible capacity remained steady at 174 mAh g(-1). These impressive outcomes are due to the robust coupling between the CoFe2O4 nanoparticles and SNRGO within the nanocomposites.
引用
收藏
页数:8
相关论文
共 38 条
[1]   Controllable synthesis of RGO/FexOy nanocomposites as high-performance anode materials for lithium ion batteries [J].
Dong, Xiangmao ;
Li, Li ;
Zhao, Chongjun ;
Liu, Hua-kun ;
Guo, Zaiping .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (25) :9844-9850
[2]   Hybrid materials of graphene anchored with CoFe2O4 for the anode in sodium-ion batteries [J].
Feng, Jian-Min ;
Zhong, Xia-Hua ;
Wang, Gui-Zhi ;
Dong, Lei ;
Li, Xi-Fei ;
Li, De-Jun .
JOURNAL OF MATERIALS SCIENCE, 2017, 52 (06) :3124-3132
[3]   TiO2 nanorods anchor on reduced graphene oxide (R-TiO2/rGO) composite as anode for high performance lithium-ion batteries [J].
Fu, Yuan-Xiang ;
Dai, Yao ;
Pei, Xian-Yinan ;
Lyu, Shu-Shen ;
Heng, Yi ;
Mo, Dong-Chuan .
APPLIED SURFACE SCIENCE, 2019, 497
[4]   Bimetallic Antimony-Vanadium Oxide Nanoparticles Embedded in Graphene for Stable Lithium and Sodium Storage [J].
Hao, Yutong ;
Jiang, Ying ;
Zhao, Luzi ;
Ye, Zhengqing ;
Wang, Ziheng ;
Chu, Ditong ;
Wu, Feng ;
Li, Li ;
Xie, Man ;
Chen, Renjie .
ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (18) :21127-21137
[5]   Synthesis and characterization of CoFe2O4@TiO2@HKUST-1 as a novel metal-organic framework nanocomposite [J].
Heydari, Maryam ;
Gharagozlou, Mehrnaz ;
Ghahari, Mehdi ;
Sadjadi, Samahe .
INORGANIC CHEMISTRY COMMUNICATIONS, 2021, 130
[6]   Advances and Challenges in Metal Sulfides/Selenides for Next-Generation Rechargeable Sodium-Ion Batteries [J].
Hu, Zhe ;
Liu, Qiannan ;
Chou, Shu-Lei ;
Dou, Shi-Xue .
ADVANCED MATERIALS, 2017, 29 (48)
[7]   Sodium storage behavior and long cycle stability of boron-doped carbon nanofibers for sodium-ion battery anodes [J].
Jeon, Injun ;
Yang, Dingcheng ;
Yadav, Dolly ;
Seo, Jangwon ;
Zhang, Hongwei ;
Yin, Linghong ;
Ahn, Hyung Soo ;
Cho, Chae-Ryong .
ELECTROCHIMICA ACTA, 2023, 439
[8]   A Brief Review of Post-Lithium-Ion Batteries [J].
Kulova, Tatiana L. ;
Fateev, Vladimir N. ;
Seregina, Ekaterina A. ;
Grigoriev, Alexander S. .
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2020, 15 (08) :7242-7259
[9]   In Situ Grown Fe2O3 Single Crystallites on Reduced Graphene Oxide Nanosheets as High Performance Conversion Anode for Sodium-Ion Batteries [J].
Li, Ting ;
Qin, Aiqiong ;
Yang, Lanlan ;
Chen, Jie ;
Wang, Qiufan ;
Zhang, Daohong ;
Yang, Hanxi .
ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (23) :19900-19907
[10]   Flexible CoFe2O4 nanoparticles/N-doped carbon nanofibers membrane as self-standing anode for lithium-ion batteries [J].
Li, Xiaoqiang ;
Guan, Guangguang ;
Zhang, Kaiyin ;
Gao, Guojun ;
Xiang, Jun .
JOURNAL OF ALLOYS AND COMPOUNDS, 2023, 946