Middle Triassic Cu-Pb-Zn Skarn mineralization in the Wulonggou gold ore field, Eastern Kunlun Orogen, NW China: Insights from phlogopite Ar-Ar and zircon U-Pb dating and Sr-Nd-Pb-Hf isotopes

The skarn is one of the most significant Cu-Pb-Zn mineralization worldwide. The timing of the magmatic-hydrothermal activity is of importance for understanding the Cu-Pb-Zn mineralization process. The Cu-Pb-Zn skarn mineralization has been recognized in the northwestern section of the Wulonggou gold ore field, Eastern Kunlun Orogen (EKLO), NW China. However, no precise geochronological data has been measured for the Cu-Pb-Zn mineralization, and the source of ore-forming materials is also not well studied. In this study, we present new LA-ICPMS U-Pb ages and Sr-Nd-Hf isotopic compositions for granodiorite and diorite in the northern section of the Wulonggou gold ore field, as well as an Ar-Ar age for phlogopite and Pb isotopic compositions for sulfides and intrusions, further to constrain the ages of mineralization and magmatism, and the source of ore-forming materials. Two granodiorite samples yield mean ages of 245 +/- 2 to 243 +/- 2 Ma and a diorite has a mean age of 245 +/- 2 Ma. A phlogopite sample, which is associated with Cu-Pb-Zn mineralization, has been chosen to precisely date the formation of Cu-Pb-Zn ores by Ar-Ar method and yields a well-defined plateau age of 240.4 +/- 1.2 Ma. These results indicate that the Cu-Pb-Zn skarn mineralization formed in the Middle Triassic and is closely related to the coeval magmatism. The epsilon(Hf)(t) values of the ore-related granodioritic and dioritic rocks range from -2.8 to +2.5, whereas an un-mineralized granodiorite sample (WHFG-1) shows lower epsilon(Hf)(t) values of -9.3 to -3.4, indicating that these magmatic rocks are derived from the mixing of magma with different proportions of mantle- and crust-components. A mixing model with similar to 40-70 % mantle contribution involved in the formation of ore-related granodiorite and diorite was revealed by Sr-Nd-Hf isotopic compositions. Combined with Pb isotopic compositions for sulfides, feldspar, and bulk rocks, we consider a common source for the ore-forming materials and magmatism. In addition, higher epsilon(Hf)(t) and epsilon(Nd)(t) values for ore-related magmatism implicate that mantle-derived melts show a vital role in the Cu-Pb-Zn skarn mineralization process.