Multifunctional antibacterial cotton fabrics based on a triazole-halamine-diethyl phosphite

被引:1
作者
Li, Lifan [1 ]
Zhou, Deming [1 ]
Zhu, Yifan [2 ]
Zhang, Tonghua [1 ]
Zhang, Zaixing [3 ]
Jing, Lingxiao [1 ,4 ]
机构
[1] Southwest Univ, Coll Sericulture Text & Biomass Sci, Chongqing Engn Res Ctr Biomat Fiber & Modern Text, State Key Lab Resource Insects, Chongqing 400715, Peoples R China
[2] Australian Natl Univ, Coll Engn Comp & Cybernet, Sch Comp, Canberra 2601, Australia
[3] Huaihua Univ, Hunan Engn Lab Preparat Technol Polyvinyl Alcohol, Chem & Mat Engn Sch, Huaihua 418000, Peoples R China
[4] Yibin Pingshan Fanglian Technol Dev Co Ltd, Yibin 645350, Peoples R China
关键词
Cotton fabrics; N-halamine; Antibacterial properties; Flame retardancy; Hydrophobicity; CELLULOSE;
D O I
10.1016/j.indcrop.2024.119571
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Cotton fabrics has the disadvantages of flammability and breed bacteria, resulting in a risk to the life and health of the user. Hence, it is necessary to address the problems and also can create value-added products at the same time. In this work, a Triazole-halamine-diethyl phosphite (NABTA-DEP) was initially synthesized, followed by its application to cotton fabrics via the thiol-ene click reaction. This preparation process resulted in a multifunctional antibacterial cotton fabrics after chlorination (Cotton-NABTA-DEP-Cl). The results proved that NABTADEP was successfully synthesized and grafted onto cotton fabrics. Based on the effect of N-halamine and triazole structures, the antibacterial testing results showed that almost all of S. aureus and E. coli onto the modified cotton were inactivated at a concentration of 5 g/L. The modified cotton fabrics with 6.7 % grafting rate demonstrated satisfied thermal stability and the peak heat release rate (PHRR) and total heat release (THR) values decreased compared with raw cotton fabric. Additionally, loading of 3-mercaptopropyltriethoxysilane (MPTES) could enhance hydrophobicity, which decreased slightly after chlorination, water contact angle (WCA) at 3 s from 131 degrees to 127.5 degrees . The paper offers valuable insights for the development of multifunctional cotton fabrics and expands the application scope.
引用
收藏
页数:9
相关论文
共 42 条
[1]   Flame retardant, antistatic cotton fabrics crafted by layer-by-layer assembly [J].
An, Wen ;
Ma, Jianzhong ;
Xu, Qunna ;
Fan, Qianqian .
CELLULOSE, 2020, 27 (14) :8457-8469
[2]   Preparation of quaternarized N-halamine-grafted graphene oxide nanocomposites and synergetic antibacterial properties [J].
Bu, Danlin ;
Zhou, Yu ;
Yang, Chang ;
Feng, Hengyu ;
Cheng, Chunxia ;
Zhang, Mengjie ;
Xu, Zice ;
Xiao, Linghan ;
Liu, Yujing ;
Jin, Zhenai .
CHINESE CHEMICAL LETTERS, 2021, 32 (11) :3509-3513
[3]   Hydrophobization of cotton fabric by Gliding Arc plasma discharge [J].
Cerny, Pavel ;
Bartos, Petr ;
Olsan, Pavel ;
Spatenka, Petr .
CURRENT APPLIED PHYSICS, 2019, 19 (02) :128-136
[4]   Preparation, characterization, and antibacterial activities of quaternarized N-halamine-grafted cellulose fibers [J].
Chen, Xiaoqin ;
Liu, Zuliang ;
Cao, Weiwei ;
Yong, Chunyan ;
Xing, Xiaodong .
JOURNAL OF APPLIED POLYMER SCIENCE, 2015, 132 (43)
[5]   Alginate modification via click chemistry for biomedical applications [J].
Deng, Yaling ;
Shavandi, Amin ;
Okoro, Oseweuba Valentine ;
Nie, Lei .
CARBOHYDRATE POLYMERS, 2021, 270
[6]   Facile Generation of Durable Superhydrophobic Fabrics toward Oil/Water Separation via Thiol-Ene Click Chemistry [J].
Fang, Yuanfeng ;
Liu, Chun ;
Li, Meng ;
Miao, Xiaomei ;
Pei, Yongbing ;
Yan, Yue ;
Xiao, Wenjun ;
Wu, Lianbin .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2020, 59 (13) :6130-6140
[7]   Multifunctional cotton non-woven fabrics coated with silver nanoparticles and polymers for antibacterial, superhydrophobic and high performance microwave shielding [J].
Gao, Ya-Nan ;
Wang, Ye ;
Yue, Tian-Ning ;
Weng, Yun-Xuan ;
Wang, Ming .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2021, 582 :112-123
[8]   Antimicrobial textile: recent developments and functional perspective [J].
Gulati, Rehan ;
Sharma, Saurav ;
Sharma, Rakesh Kumar .
POLYMER BULLETIN, 2022, 79 (08) :5747-5771
[9]   Construction of durable flame-retardant and robust superhydrophobic coatings on cotton fabrics for water-oil separation application [J].
Guo, Wenwen ;
Wang, Xin ;
Huang, Jiali ;
Zhou, Yifan ;
Cai, Wei ;
Wang, Junling ;
Song, Lei ;
Hu, Yuan .
CHEMICAL ENGINEERING JOURNAL, 2020, 398
[10]   Synthesis of novel reactive N-halamine precursors and application in antimicrobial cellulose [J].
Jiang, Zhiming ;
Ma, Kaikai ;
Du, Jinmei ;
Li, Rong ;
Ren, Xuehong ;
Huang, T. S. .
APPLIED SURFACE SCIENCE, 2014, 288 :518-523