Magnetic wrinkled organosilica-based metal-enzyme integrated catalysts for enhanced chemoenzymatic catalysis

被引：3

作者：

Liu, Yunting ^{[1
,2
]}

Guo, Na ^{[1
]}

Kong, Weixi ^{[1
]}

Gao, Shiqi ^{[1
]}

Liu, Guanhua ^{[1
]}

Zhou, Liya ^{[1
]}

Gao, Jing ^{[1
]}

Jiang, Yanjun ^{[1
,2
]}

机构：

[1] Hebei Univ Technol, Sch Chem Engn & Technol, Tianjin 300130, Peoples R China

[2] Hebei Univ Technol, Tianjin Key Lab Chem Proc Safety, Tianjin 300130, Peoples R China

来源：

GREEN SYNTHESIS AND CATALYSIS | 2024年 / 5卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Magnetic wrinkled organosilica; Chemoenzymatic catalysis; Co-immobilization; Asymmetric synthesis; Chiral amines/alcohols; Dynamic kinetic resolution; Nanomaterials; DYNAMIC KINETIC RESOLUTION; MESOPOROUS SILICA; RADIAL WRINKLE; AMINES; COIMMOBILIZATION; NANOPARTICLES; RACEMIZATION; ALCOHOLS;

D O I：

10.1016/j.gresc.2023.01.008

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Core-shell structured magnetic wrinkled organosilica-based metal-enzyme integrated catalysts were synthesized, and their catalytic performances were studied in the chemoenzymatic dynamic kinetic resolution of chiral amines in an organic solvent, as well as in the chemoenzymatic synthesis of chiral alcohols in water. Structureperformance studies revealed the important influence of their tunable structure and composition on the optimization of activity, stability, and recyclability in chemoenzymatic catalysis.

引用

页码：122 / 125

页数：4

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