Removal of heavy metal ions from wastewater using ion exchange resin in a batch process with kinetic isotherm

被引:34
作者
Jasim, Ansam Qays [1 ]
Ajjam, Sata Kathum [1 ]
机构
[1] Univ Babylon, Coll Engn, Chem Engn Dept, Babylon, Iraq
关键词
Wastewater; Lead; Copper; Cation exchange resin; ASSISTED OXIDATIVE DESULFURIZATION; OPTIMIZATION; COPPER; LEAD;
D O I
10.1016/j.sajce.2024.04.002
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Techniques such as selective ion exchange can be used to remove traces of heavy metals. The recently created resins provided quicker sorption kinetics and a high resin capacity for metal ions such as Lead (Pb2*), 2 *), Copper (Cu2*), 2 *), Zinc (Zn2*), 2 *), Cadmium (Cd2*), 2 *), and Nickel (Ni2*) 2 *) ions. The elimination of Pb2* 2 * and Cu2* 2 * ions from aqueous solutions was examined in the current work. Purolite (R) (R) C100, a strong acid cation-exchange resin, was used in experimental studies. Using packed-column chromatography, the impacts of operating factors on metal ion exchange were examined. These parameters included resin dose, initial pH, residence time, and metal ion concentration with ranges of 40- 80 gs, 3- 12, 30- 90 min, and 50-150 parts per million respectively. As part of exchange research, different doses of resin are brought into contact with a fixed volume of solution containing different concentrations and pHs of Pb2* 2 * and Cu2* 2 * ions for different periods. An Atomic Absorption Spectrophotometer (AAS) approach was used to measure the concentrations of metal ions. Experimental data on ion exchange were evaluated using Langmuir, Freundlich, and Temkin models. The results showed that there is a clear competition between lead and copper, as it was found that there is a convergence between the removal rates for both metals under the same conditions. The ion-exchange recovery of Cu approached 94.37 %, but Pb recovery was 92.9 % with Purolite (R) (R) C100 resin dose range of 40 g to 80 g in the pH range of 3 to 12.
引用
收藏
页码:43 / 54
页数:12
相关论文
共 25 条
[1]   Oxidative desulfurization of model fuel using a NiO-MoO3 catalyst supported by activated carbon: Optimization study [J].
Abdulhadi, Sura Ahmed ;
Alwan, Hameed Hussein .
SOUTH AFRICAN JOURNAL OF CHEMICAL ENGINEERING, 2023, 43 :190-196
[2]   Removal of some heavy metal cations by synthetic resin purolite C100 [J].
Abo-Farha, S. A. ;
Abdel-Aal, A. Y. ;
Ashour, I. A. ;
Garamon, S. E. .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 169 (1-3) :190-194
[3]  
Al Jaberi F.Y., 2020, AIP C PROC AIP PUBLI, P1, DOI [10.1063/5.0000157, DOI 10.1063/5.0000157]
[4]   Extensive Study of Electrocoagulation-Based Adsorption Process of Real Groundwater Treatment: Isotherm Modeling, Adsorption Kinetics, and Thermodynamics [J].
Aljaberi, Forat Yasir .
WATER, 2024, 16 (04)
[5]   Electrocoagulation removal of Pb, Cd, and Cu ions from wastewater using a new configuration of electrodes [J].
AlJaberi, Forat Yasir ;
Hawaas, Zahraa Alaa .
METHODSX, 2023, 10
[6]  
Aljaleel Marwa Abd, 2022, 2022 2nd International Conference on Advances in Engineering Science and Technology (AEST), P111, DOI 10.1109/AEST55805.2022.10413162
[7]   Functionalized soy waste biomass - A novel environmental-friendly biosorbent for the removal of heavy metals from aqueous solution [J].
Bulgariu, Laura ;
Bulgariu, Dumitru .
JOURNAL OF CLEANER PRODUCTION, 2018, 197 :875-885
[8]   Optimization analysis of mixing-assisted oxidative desulfurization of model sulfur compounds using commercial ferrate(VI) [J].
Choi, Angelo Earvin Sy ;
Roces, Susan ;
Dugos, Nathaniel ;
Futalan, Cybelle Morales ;
Wan, Meng-Wei .
DESALINATION AND WATER TREATMENT, 2016, 57 (37) :17616-17623
[9]   Optimization of ultrasound-assisted oxidative desulfurization of model sulfur compounds using commercial ferrate (VI) [J].
Choi, Angelo Earvin Sy ;
Roces, Susan ;
Dugos, Nathaniel ;
Futalan, Cybelle Morales ;
Lin, Shiow-Shyung ;
Wan, Meng-Wei .
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2014, 45 (06) :2935-2942
[10]  
Das Shilpi., 2014, Batch Study Removal of Copper Ions From Water By Using Ion Exchange Resin