Fabrication of Strontium Molybdate with Functionalized Carbon Nanotubes for Electrochemical Determination of Antipyretic Drug-Acetaminophen

被引:0
作者
Khandagale, Dhanashri D. [1 ]
Wang, Sea-Fue [1 ]
机构
[1] Natl Taipei Univ Technol, Dept Mat & Mineral Resources Engn, Taipei 106, Taiwan
关键词
screen-printed carbon electrode; acetaminophen; synergistic effect; SrMoO4@f-CNF; electrochemical sensor; DOPED GRAPHENE; SENSOR; NANOCOMPOSITE; PARACETAMOL; SRMOO4;
D O I
10.3390/ma17122887
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In recent years, there has been a significant interest in the advancement of electrochemical sensing platforms to detect antipyretic drugs with high sensitivity and selectivity. The electrochemical determination of acetaminophen (PCT) was studied with strontium molybdate with a functionalized carbon nanotube (SrMoO4@f-CNF) nanocomposite. The SrMoO4@f-CNF nanocomposite was produced by a facial hydrothermal followed by sonochemical treatment, resulting in a significant enhancement in the PCT determination. The sonochemical process was applied to incorporate SrMoO4 nanoparticles over f-CNF, enabling a network-like structure. Moreover, the produced SrMoO4@f-CNF composite structural, morphological, and spectroscopic properties were confirmed with XRD, TEM, and XPS characterizations. The synergistic effect between SrMoO4 and f-CNF contributes to the lowering of the charge transfer resistance (R-ct = 85 ohm center dot cm(2)), a redox potential of E-pc = 0.15 V and E-pa = 0.30 V (vs. Ag/AgCl), and a significant limit of detection (1.2 nM) with a wide response range of 0.01-28.48 mu M towards the PCT determination. The proposed SrMoO4@f-CNF sensor was studied with differential pulse voltammetry (DPV) and cyclic voltammetry (CV) techniques and demonstrated remarkable electrochemical properties with a good recovery range in real-sample analysis.
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页数:14
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