(H3dien)[Ni(NO3)(C2O4)2].2H2O: Synthesis, crystal structure, catalytic activity and magnetic study

被引：6

作者：

Akouibaa, Mohamed ^{[1
]}

Hassani, Hicham Oudghiri ^{[1
]}

Ouarsal, Rachid ^{[1
]}

Rakib, Souad ^{[1
]}

Lachkar, Mohammed ^{[1
]}

Poupon, Morgane ^{[2
]}

Dusek, Michal ^{[2
]}

Morley, Nicola ^{[3
]}

El Bali, Brahim

机构：

[1] Univ Sidi Mohamed Ben Abdellah, Fac Sci, Engn Lab Organometall & Mol Mat, POB 1796 Atlas, Fes 30000, Morocco

[2] Czech Acad Sci, Inst Phys, Slovance 2,8, Prague 18221, Czech Republic

[3] Univ Sheffield, Dept Mat Sci & Engn, Sheffield S1 3JD, S Yorkshire, England

来源：

CHEMICAL DATA COLLECTIONS | 2022年 / 42卷

关键词：

Hybrid material; Crystal structure; Spectroscopy; Magnetism; Catalysis; HIRSHFELD SURFACE-ANALYSIS; SOLVENT-FREE SYNTHESIS; COPPER(II) COMPLEXES; HYDROGEN-BOND; DNA-BINDING; NANOPARTICLES; FRAMEWORKS; OXALATES; SPECTRA; NI;

D O I：

10.1016/j.cdc.2022.100969

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex (H(3)dien)[Ni(NO3)(C2O4)(2)].2H(2)O, with (dien) is the diethylenetriamine (NH2CH2CH2)(2)NH, and was synthesized in solution. It was characterized using single-crystal X-ray diffraction, Infrared (FT-IR) and UV-Visible spectroscopies, and TG-DTA thermal analysis. FT-IR confirmed the characteristic bands of diethylenetriamine, nitrate and oxalate groups. (H(3)dien)[Ni(NO3)(C2O4)(2)].2H(2)O crystallizes into the monoclinic system (P2(1)/c). Nickel has a square-based pyramidal NiO5 coordination. O-H...O and N-H...O H-bonds connect ionic entities and water molecules into bc-plane-parallel slabs. The UV-Visible spectrum shows absorption bands compatible with a six-coordinated high-spin octahedral Ni(II). Magnetization and a.c. susceptibility measurements were measured. The catalytic efficiency of the title compound in the reduction by NaBH4 of three nitrophenol isomers to their corresponding aminophenols was tested.

引用

页数：17

共 80 条

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Agilent, 2010, CrysAlis PRO

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