Solid - phase equilibria and thermodynamic properties of the Sb-Te-S system

被引：2

作者：

Aliyev, F. R. ^{[1
]}

Orujlu, E. N. ^{[1
]}

Mashadiyeva, L. F. ^{[1
,2
]}

Dashdiyeva, G. B. ^{[1
,3
]}

Babanly, D. M. ^{[1
,2
,4
]}

机构：

[1] Azerbaijan State Oil & Ind Univ ASOIU, Baku, Azerbaijan

[2] Inst Catalysis & Inorgan Chem ICIC, Baku, Azerbaijan

[3] Baku Engn Univ BEU, Baku, Azerbaijan

[4] French Azerbaijani Univ UFAZ, Baku, Azerbaijan

来源：

PHYSICS AND CHEMISTRY OF SOLID STATE | 2024年 / 25卷 / 01期

基金：

英国科研创新办公室;

关键词：

antimony sulfide; antimony telluride; Sb; 2; Te; S; tetradymite; EMF measurements; thermodynamic properties; THERMOELECTRIC PROPERTIES; SB2TE2SE;

D O I：

10.15330/pcss.25.1.26-34

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The powder X-ray diffraction (PXRD) analysis and the electromotive force (emf) measurements have been used to investigate the Sb - Te - S system in the Sb 2 S 3 -Sb 2 Te 3 -Te-S composition region at 300 - 450 K temperatures interval. Relative partial molar functions of antimony in alloys have been calculated and obtained data have been used to get self -consistent sets of the standard Gibbs free energy, standard enthalpy, and standard entropy of the Sb 2 S 3 and Sb 2 Te 2 S compounds, as well as the Sb 2 Te 2,4 S 0,6 and Sb 2 Te 2,7 S 0,3 solid solutions. The data obtained for Sb 2 S 3 have been compared to the ones available in the literature. Thermodynamic functions of the Sb 2 Te 2 S compound, as well as the Sb 2 Te 2,4 S 0,6 and Sb 2 Te 2,7 S 0,3 solid solutions have been determined for the first time.

引用

页码：26 / 34

页数：9

共 53 条

[1] A DFT based first-principles investigation of optoelectronic and structural properties of Bi2Te2Se [J].

Afzal, Md Asif ;

Naqib, S. H. .

PHYSICA SCRIPTA, 2021, 96 (04)

[2] Thermodynamic Properties of the Chalcogenide Phases in the Bi-Te-S System [J].

Ahmadov, E. J. ;

Babanly, D. M. ;

Imamaliyeva, S. Z. ;

Tagiev, D. B. ;

Babanly, M. B. .

INORGANIC MATERIALS, 2021, 57 (03) :227-233

[3] Solid-phase equilibria in the GeBi2Te4-Bi2Te3-Te system and thermodynamic properties of compounds of the GeTe•mBi2Te3 homologous series [J].

Alakbarova, T. M. ;

Orujlu, E. N. ;

Babanly, D. M. ;

Imamaliyeva, S. Z. ;

Babanly, M. B. .

PHYSICS AND CHEMISTRY OF SOLID STATE, 2022, 23 (01) :25-33

[4] Thermodynamic study of antimony chalcoiodides by EMF method with an ionic liquid [J].

Aliev, Ziya Sakhaveddin ;

Musayeva, Sabina Sahib ;

Imamaliyeva, Samira Zakir ;

Babanly, Mahammad Baba .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2018, 133 (02) :1115-1120

[5]

Aliyev F., 2022, Nova Science Publishers Properties and Uses of Antimony, V73, DOI [10.52305/BMLN5323, DOI 10.52305/BMLN5323]

[6]

Aliyev FR, 2023, NEW MATER COMPOUND A, V7, P76

[7]

Aliyev F.R., 2021, AZERB CHEM J, V4, P53, DOI [10.32737/0005-2531-2021-4-53-59, DOI 10.32737/0005-2531-2021-4-53-59]

[8] Thermodynamic functions of arsenic selenides [J].

Babanly, D. M. ;

Velieva, G. M. ;

Imamaliyeva, S. Z. ;

Babanly, M. B. .

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2017, 91 (07) :1170-1173

[9]

Babanly M, 1985, Mathematical Problems in Chemical Thermodynamics, P192

[10] Some Issues of Complex Studies of Phase Equilibria and Thermodynamic Properties in Ternary Chalcogenide Systems Involving Emf Measurements (Review) [J].

Babanly, M. B. ;

Mashadiyeva, L. F. ;

Babanly, D. M. ;

Imamaliyeva, S. Z. ;

Tagiev, D. B. ;

Yusibov, Yu. A. .

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 64 (13) :1649-1671

← 1 2 3 4 5 6 →