Transition Metal Catalyzed Carbocycle-Selective Asymmetric Hydrogenation of Aromatic Rings

被引：7

作者：

Chen Qian ^{[1
,2
]}

Han Zhaobin ^{[2
]}

Ding Kuiling ^{[2
,3
,4
]}

机构：

[1] Univ Shanghai Sci & Technol, Sch Mat & Chem, Shanghai 200093, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

[3] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China

[4] Shanghai Jiao Tong Univ, Frontiers Sci Ctr Transformat Mol, Shanghai 200240, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 44卷 / 07期

基金：

国家重点研发计划; 中国国家自然科学基金;

关键词：

transition metal; (hetero)arene; asymmetric hydrogenation; dearomatization; DIRECTED DIASTEREOSELECTIVE HYDROGENATION; ARENE HYDROGENATION; HOMOGENEOUS HYDROGENATION; RUTHENIUM NANOPARTICLES; RHODIUM; LIGANDS; STABILIZERS; REACTIVITY; REDUCTION; INHIBITOR;

D O I：

10.6023/cjoc202403017

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Asymmetric hydrogenation of carbon rings in (hetero)arenes is one of the most direct and efficient methods for preparing saturated and partially saturated chiral six membered carbon ring compounds. While significant challenges in terms of low reactivity and selectivity remain, some breakthroughs have been made in this field of carbocycle-selective asymmetric hydrogenation of (hetero)arenes in recent years. The research progress of transition metal catalyzed carbocycle-selective asymmetric hydrogenation of (hetero)arenes in the past few decades is summarized, and the prospects of further developments are also discussed.

引用

页码：2063 / 2076

页数：14

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