Synergetic engineering of ZnS/In2Te3 heterostructure for efficient oxygen evolution reaction

被引:0
作者
Alothman, Asma A. [1 ]
Kumar, Ome Parkash [2 ]
Madni, Muhammad [3 ]
Ahmad, Imran [3 ]
Mohammad, Saikh [1 ]
Saleem, Shahroz [4 ]
Abid, Abdul Ghafoor [3 ]
机构
[1] King Saud Univ, Coll Sci, Dept Chem, Riyadh, Saudi Arabia
[2] Islamia Univ Bahawalpur, Inst Chem, Baghdad Ul Jadeed Campus, Bahawalpur, Pakistan
[3] Bahauddin Zakariya Univ, Inst Chem Sci, Multan, Pakistan
[4] Shaanxi Normal Univ, Sch Mat Sci & Engn, Xian, Peoples R China
关键词
BET; double layer capacitance; electrocatalyst; oxygen evolution; ZnS/In2Te3; BIFUNCTIONAL ELECTROCATALYST; METAL OXIDES; CATALYSTS;
D O I
10.1111/ijac.14823
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The potential of electrochemical water splitting to tackle energy and environmental issues has garnered substantial interest. In the present work, an effective ZnS/In2Te3 has been constructed by hydrothermal support on a stainless-steel strip and explored for oxygen evolution. The addition of ZnS modifies the band structure of In2Te3 and enhances its specific conductivity and capacitance on an intrinsic level, making rapid ion transportation. The optimized ZnS/In2Te3 displayed efficient oxygen evolution reaction (OER) performance with an overpotential of 228 mV and a Tafel slope of 111 mV dec(-1) with cyclic activity up to 1000 cycles in 1 M KOH solution. ZnS/In2Te3 has a large surface area (28 m(3)g(-1)) and a charge capacitance of (.037 mF), according to studies using Brunauer-Emmett-Teller and double-layer capacitance. Combining several strategies improves overall electrochemical performance of ZnS/In2Te3, making it a promising option for use in state-of-the-art OER.
引用
收藏
页码:4156 / 4167
页数:12
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